Cyclohexyl Rings in Spatial Proximity: Stereochemistry of Tricyclohexylmethane
The static and dynamic stereochemistry of tricyclohexylmethane (2) is analyzed.The 13C nad 1H NMR of 2 were assigned by means of the 2D NMR techniques INADEQUATE and DQF COSY.Molecular mechanics calculations were performed in order to estimate the influen
Tricyclohexylmethane has a melting point close to ambient temperature.Nevertheless the X-ray structure has been determined.The crystal is chiral but its chirality could not be established.The solid is unusual in that the atomic volume per carbon atoms is
Gillies, D. G.,Luff, S.,Smith, G. W.,Sutcliffe, L. H.
Radical deoxygenation of tertiary alcohols via trifluoroacetates
Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.
Kim, Joong-Gon,Cho, Dae Hyan,Jang, Doo Ok
p. 3031 - 3033
(2007/10/03)
CATALYTIC CONVERSIONS OF TRICYCLOHEXYLMETHANE.
The authors have achieved low-temperature catalytic isomerization of tricyclohexylmethane under the influence of Lewis acids, special attention being devoted to formation of tricyclic structures of the admantane type. It is found that the effects of alumi
Gavrilov,Kosnikovskaya,Muratalieva
p. 123 - 126
(2007/10/02)
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