- Synthesis of tetramers of 1,3-adamantane derivatives
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Novel tetramers of 1,3-adamantane and 5,7-dibutyl-1,3-adamantane were synthesized by the coupling reaction of 3-bromo-1,1′-biadamantane or 3-bromo-5,5′,7,7′-tetrabutyl-1,1′-biadamantane with sodium in n-octane or with magnesium in diethyl ether. Although
- Ishizone, Takashi,Tajima, Hiroyuki,Matsuoka, Shinichi,Nakahama, Seiichi
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- Synthesis of rigid cores based on 1,1′-biadamantane
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An efficient strategy has been developed for the preparation of a series of rigid cores based on 1,1′-biadamantane. Disproportionation of bromobenzene in the alkylation was observed through the effect of AlCl3 or AlBr3. Proposed mechanisms of these reactions have also been outlined on the basis of the results obtained.
- Lai, Xiangfeng,Guo, Jianwei,Fu, Shuqin,Zhu, Dongyu
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p. 8677 - 8680
(2016/02/05)
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