- POLYMERIZABLE DERIVATIVES OF TRIPHENYLPHOSPHINE. ACYLATION OF TRIARYLPHOSPHINES BEARING ALCOHOL OR AMINE SUBSTITUENTS WITH ACRYLOYLCHLORIDE AND METHACRYLOYLCHLORIDE
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Methods to prepare amino substituted triaryl-phosphines viz.N-methyl-2-(diphenylphosphino)benzylamine, N-t-butyl-2-(diphenylphosphino)benzylamine and α,N-dimethyl-4-(diphenylphosphino)benzylamine are presented.The acylation of amino and alcohol substituted triarylphosphines have been studied and the amides N-methacryloyl-N-methyl-4-(diphenylphosphino)benzylamine, N-methacryloyl-2-(diphenylphosphino)aniline, N-methacryloyl-N-methyl-4-(diphenylphosphino)benzylamine, N-methyl-N-propionyl-4-(diphenylphosphino)benzylamine, N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine and N-acryloyl-N-methyl-4-(diphenylphosphino)benzylamine and the ester 2-(diphenylphosphino)benzyl methacrylate have been prepared. Key words: Phosphine; monomer; acylation; acryloylchloride; methacryloylchloride polymer-bound.
- Nikitidis, Antonios,Andersson, Carlaxel
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p. 141 - 152
(2007/10/02)
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