- Efficient encapsulation of chloroform with cryptophane-M and the formation of exciplex studied by fluorescence spectroscopy
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Efficient encapsulation of small molecules with supermolecules is one of significantly important subjects due to strong application potentials. This article presents the interaction between cryptophane-M and chloroform by fluorescence spectroscopy. The so
- Shi, Yanqi,Li, Xueming,Yang, Jianchun,Gao, Fang,Tao, Chuanyi
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- Two-step synthesis of D3 and C3h cryptophanes
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Dihalides X-(Z)-X, [Z = (CH2)n; n = 1-7 or CH 2CH=CHCH2] react with the phenol group of vanillyl alcohol to give the dialkylated derivatives HOCH2-Ar-O-(Z)-O-Ar-CH 2OH (2), which in turn, in the presence of formic acid, afford the corresponding D3 cryptophanes (3), with, in some cases, minor amounts of the C3h isomers (4).
- Canceill, Josette,Collet, Andre
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p. 582 - 584
(2007/10/02)
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