A NOVEL APPROACH TO α-KETO ACID DERIVATIVES VIA PALLADIUM-CATALYZED ARYLATION AND VINYLATION OF METHYL α-METHOXYACRYLATE
Methyl α-methoxyacrylate reacts stereoselectively with aryl iodides and vinyl triflates under palladium catalysis to give enol ethers of arylpyruvates and of β,γ-unsaturated α-keto esters in good to moderate yields.
Cacchi, Sandro,Ciattini, Pier Giuseppe,Morera, Enrico,Ortar, Giorgio
p. 3039 - 3042
(2007/10/02)
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