Dienophilie des olefines captodatives: influence de l'encombrement sterique des α-alkylthioacrylonitriles sur la stereoselectivite des reactions de Diels-Alder
The Diels-Alder reaction of cyclopentadiene with a series of α-alkyl-(or aryl)-thioacrylonitriles were investigated.The spontaneous cycloaddition occurs at room temperature affording adducts in excellent yield.The stereochemical assignments of the adducts
Boucher, Jean-Luc,Stella, Lucien
p. 276 - 282
(2007/10/02)
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