Axial 4,4′,6,6′-tetrakis-trifluoromethyl-biphenyl-2, 2′diamine (TF-BIPHAM): Resolution and applications in asymmetric hydrogenation
(Equation Presented) The racemic TF-BIPHAM was resolved for the first time, and the effectiveness of the resolved diamine was demonstrated by highly enantioselective hydrogenation of α-aryl enamides and α-dehydroamino acid esters using readily accessible
Wang, Chun-Jiang,Gao, Feng,Liang, Gang
supporting information; experimental part
p. 4711 - 4714
(2009/05/31)
MAGNESIUM-METHANOL AS A SIMPLE CONVENIENT REDUCING AGENT FOR Α,Β-UNSATURATED ESTERS
Various α,β-unsaturated esters undergo double bond reduction by magnesium in methanol to give the corresponding saturated ones in almost quantitative yields.
Youn, In Kwon,Yon, Gyu Hwan,Pak, Chwang Siek
p. 2409 - 2410
(2007/10/02)
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