Regio- and chemoselective multiple functionalization of pyrimidine derivatives by selective magnesiations using TMPMgCl·LiCl
(Chemical Equation Presented) Successive regio- and chemoselective magnesiations of pyrimidines using TMPMgCl·LiCl furnish, after trapping with various electrophiles, highly functionalized derivatives in good to excellent yields. Applications to the synth
Mosrin, Marc,Knochel, Paul
supporting information; experimental part
p. 2497 - 2500
(2009/05/30)
Multiple regio- and chemoselective functionalizations of pyrimidine derivatives using TMPMgCl·LiCl and TMP2Mg·2 LiCl
The multiple successive regio- and chemoselective magnesiation of commercially available 2-bromopyrimidine at the C4, C6, and C5 positions allows the regioselective functionalization of all positions of the pyrimidine ring. Georg Thieme Verlag Stuttgart ·
Mosrin, Marc,Petrera, Marilena,Knochel, Paul
experimental part
p. 3697 - 3702
(2009/08/07)
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