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Bromomethyltrimethylsilane

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Name

Bromomethyltrimethylsilane

EINECS N/A
CAS No. 18243-41-9 Density 1.165 g/cm3
PSA 0.00000 LogP 2.67700
Solubility N/A Melting Point N/A
Formula C4H11BrSi Boiling Point 116.5 °C at 760 mmHg
Molecular Weight 167.121 Flash Point 16.1 °C
Transport Information UN 2924 3/PG 2 Appearance N/A
Safety 26-36/37/39-45 Risk Codes 11-34
Molecular Structure Molecular Structure of 18243-41-9 ((BROMOMETHYL)TRIMETHYLSILANE) Hazard Symbols FlammableF, CorrosiveC
Synonyms

(Trimethylsilyl)methylbromide;[Trimethyl][bromomethyl]silane;

Article Data 2

Bromomethyltrimethylsilane Specification

The Bromomethyltrimethylsilane is an organic compound with the formula C4H11BrSi. The IUPAC name of this chemical is bromomethyl(trimethyl)silane. With the CAS registry number 18243-41-9, it is also named as silane, (bromomethyl)trimethyl-. The product's categories are Si (Classes of Silicon Compounds); Si-(C)4 Compounds; Silicon Compounds (for Synthesis); Synthetic Organic Chemistry.

Physical properties about Bromomethyltrimethylsilane are: (1)ACD/LogP: 2.70; (2)ACD/LogD (pH 5.5): 2.7; (3)ACD/LogD (pH 7.4): 2.7; (4)ACD/BCF (pH 5.5): 66.1; (5)ACD/BCF (pH 7.4): 66.1; (6)ACD/KOC (pH 5.5): 699.02; (7)ACD/KOC (pH 7.4): 699.02; (8)#Freely Rotating Bonds: 1; (9)Index of Refraction: 1.429; (10)Molar Refractivity: 37.02 cm3; (11)Molar Volume: 143.4 cm3; (12)Polarizability: 14.67×10-24cm3; (13)Surface Tension: 19.7 dyne/cm; (14)Density: 1.164 g/cm3; (15)Flash Point: 16.1 °C; (16)Enthalpy of Vaporization: 34.01 kJ/mol; (17)Boiling Point: 116.5 °C at 760 mmHg; (18)Vapour Pressure: 21.6 mmHg at 25°C.

Preparation: this chemical can be prepared by chloromethyl-trimethyl-silane. This reaction will need reagent NaBr, catalyst Tetrabutylammonium bromide and solvent H2O. The reaction time is 11 days by heating. The yield is about 82%.



Uses of Bromomethyltrimethylsilane: it can be used to produce Tetramethylene[(trimethylsilyl)methyl]oxonium Tetrafluoroborate. It will need reagent silver tetrafluoroborate and solvent CH2Cl2  with reaction time of 3 days. The yield is about 74%.

When you are using this chemical, please be cautious about it as the following:
It is Highly flammable and can cause burns. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: BrC[Si](C)(C)C
(2)InChI: InChI=1/C4H11BrSi/c1-6(2,3)4-5/h4H2,1-3H3
(3)InChIKey: ACAUYCZBWABOLI-UHFFFAOYAF
(4)Std. InChI: InChI=1S/C4H11BrSi/c1-6(2,3)4-5/h4H2,1-3H3
(5)Std. InChIKey: ACAUYCZBWABOLI-UHFFFAOYSA-N

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