- 3,10-Diaminotricyclo(5.2.1.0(sup 2,6))decane
- 3,10-Dinitrophenanthrene
- 3-((10-ETHYL-11-(p-HYDROXYPHENYL)DIBENZ-(B,F)OXEPIN-3-YL)OXY)-1,2-PROPANEDIOL HYDRATE (4:1)
- 3-(1,1,2,2-Tetrafluoroethoxy)aniline
- 3-(1,1,2,2-Tetrafluoroethoxy)benzaldehyde
- 3-(1,1,2,2-Tetrafluoroethoxy)bromobenzene
- 3-(1,1,2,2-Tetrafluoroethoxy)toluene
- 3-[1,1'-Biphenyl]-4-yl-1,2,3,4-tetrahydro-1-naphthol
- 3,11-Dichloro-6,11-dihydro-6-methyldibenzo[c,f][1,2]thiazepine 5,5-dioxide
- 3-[(1,1-Dimethyl-2-hydroxyethyl)amino]-2-hydroxypropanesulfonicacid
- 335-08-0Propanenitrile,3,3,3-trifluoro-2-hydroxy-2-methyl-
- 335080-97-2Cholest-5-en-3-ol-25,26,27-13C3,(3b)- (9CI)
- 335081-04-41,2-Benzenediol,4-(2-aminoethyl-2-13C)-,hydrochloride (9CI)
- 33509-43-21,2,4-Triazin-5(2H)-one,4-amino-6-(1,1-dimethylethyl)-3,4-dihydro-3-thioxo-
- 33510-45-1Androstane-3,17-dione,3-[O-(4-nitrophenyl)oxime], (5a)- (9CI)
- 3351-05-11-Naphthalenesulfonicacid,8-(phenylamino)-5-[2-[4-[2-(3-sulfophenyl)diazenyl]-1-naphthalenyl]diazenyl]-,sodium salt (1:2)
- 33512-26-4Phosphonic acid,P-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-, diethyl ester
- 3351-28-8Chrysene, 1-methyl-
- 33512-89-93-Cyclobutene-1,2-dione,3,4-bis(phenylamino)-
- 33512-94-6Benzenecarboximidoylchloride, N-hydroxy-3-nitro-
Hot Products
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
- 7631-86-9Silicon dioxide
- 302-79-4Tretinoin
- 77-92-9Citric acid
|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
| Name |
3,3-Dimethylacryloyl chloride |
EINECS | 222-109-4 |
| CAS No. | 3350-78-5 | Density | 1.049 g/cm3 |
| PSA | 17.07000 | LogP | 1.71800 |
| Solubility | reacts with water | Melting Point |
N/A |
| Formula | C5H7ClO | Boiling Point | 146 °C at 760 mmHg |
| Molecular Weight | 118.563 | Flash Point | 51.1 °C |
| Transport Information | UN 2920 8/PG 2 | Appearance | clear colorless to yellow liquid |
| Safety | 26-36/37/39-45-16 | Risk Codes | 14-34-36/37-10 |
| Molecular Structure |
|
Hazard Symbols |
 C
|
| Synonyms |
Crotonoylchloride, 3-methyl- (7CI,8CI);Senecioyl chloride (6CI);3,3-Dimethylacrylicacid chloride;3,3-Dimethylacryloyl chloride;3,3-Dimethylacrylyl chloride;3-Methyl-2-butenoyl chloride;3-Methylcrotonoyl chloride;b,b-Dimethylacrylic acid chloride;b,b-Dimethylacryloyl chloride;b,b-Dimethylacrylyl chloride;b-Methylcrotonoyl chloride;g,g-Dimethylacryloyl chloride; |
Article Data | 70 |
3,3-Dimethylacryloyl chloride Synthetic route
| Conditions | Yield |
|---|---|
| With oxalyl dichloride In dichloromethane at 20℃; | 99% |
| With thionyl chloride at 0℃; for 3h; | 96% |
| With thionyl chloride 1.) reflux, 1.3 h, 2.) room temperature, 2.5 h, 3.) reflux, 1 h; | 92% |
| Conditions | Yield |
|---|---|
| With thionyl chloride Erhitzen des Reaktionsgemisches mit wenig Schwefelsaeure; |
- 3350-78-5
3,3-Dimethylacryloyl chloride
- 123-51-3
i-Amyl alcohol
- 56922-73-7
3-methyl-1-butyl 3-methyl-2-butenoate
| Conditions | Yield |
|---|---|
| With pyridine; dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 20℃; for 3.5h; | 100% |
| In benzene at 30℃; Kinetics; Activation energy; Further Variations:; Temperatures; Acylation; alcoholysis; | |
| With pyridine; benzene |
| Conditions | Yield |
|---|---|
| With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 2h; | 100% |
| With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 2h; | 100% |
| With pyridine | 97% |
- 3350-78-5
3,3-Dimethylacryloyl chloride
- 4020-99-9
diphenylphosphinous acid methyl ester
- 87951-17-5
(3-Methyl-2-butenoyl)diphenylphosphanoxid
| Conditions | Yield |
|---|---|
| 1) -196 deg C to r.t., 2) 2 h, r.t.; | 100% |
- 3350-78-5
3,3-Dimethylacryloyl chloride
- 13059-93-3
monohydroxymethyl-alpha-terthiophene
- 26905-76-0
5-(3-methyl-2-butenoyloxy)methyl-2,2':5',2''-terthiophene
| Conditions | Yield |
|---|---|
| With pyridine In dichloromethane | 100% |
| With pyridine In tetrahydrofuran 1.) 0 deg C, 3 h, 2.) reflux, 2h; |
- 3350-78-5
3,3-Dimethylacryloyl chloride
- 73839-45-9
(E)-trimethyl[2-(4-methylphenyl)ethenyl]silane
- 73839-46-0
(E)-1-(4-methylphenyl)-3-oxo-5-methyl-1,4-hexadiene
| Conditions | Yield |
|---|---|
| With aluminium trichloride In dichloromethane at -78℃; for 0.5h; | 100% |
- 3350-78-5
3,3-Dimethylacryloyl chloride
- 14812-60-3
2-methoxy-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
| Conditions | Yield |
|---|---|
| at 0 - 35℃; for 4h; | 100% |
| for 1h; Yield given; |
- 3350-78-5
3,3-Dimethylacryloyl chloride
- 106-40-1
4-bromo-aniline
- 135631-89-9
N-(3,3'-dimethylacryoloyl)-4-bromoaniline
| Conditions | Yield |
|---|---|
| With triethylamine In dichloromethane at 20℃; for 3.33333h; | 100% |
| Stage #1: 3,3-Dimethylacryloyl chloride; 4-bromo-aniline In dichloromethane at 20℃; for 0.333333h; Stage #2: With triethylamine In dichloromethane at 20℃; for 3h; | 100% |
| With pyridine at 0 - 20℃; for 5h; Inert atmosphere; | 99% |
- 3350-78-5
3,3-Dimethylacryloyl chloride
- 56552-80-8
(R)-3-benzyloxy-1,2-propanediol
- 349123-42-8
1,2-di(3-methylbut-2-enoyl)-3-benzyl-sn-glycerol
| Conditions | Yield |
|---|---|
| With pyridine; dmap In dichloromethane at 0 - 20℃; | 100% |
3,3-Dimethylacryloyl chloride Chemical Properties
IUPAC Name: 3-Methylbut-2-enoyl chloride
Molecular Formula: C5H7ClO
Molecular Weight: 118.56
EINECS: 222-109-4
Density: 1.049 g/cm3
Boiling Point: 145-147 ºC
Flash Point: 51 ºC
Solubility: reacts
Properties: clear colorless to yellow liquid
Freely Rotating Bonds: 1
Polar Surface Area: 17.07 Å2
Index of Refraction: 1.443
Molar Refractivity: 29.99 cm3
Molar Volume: 112.9 cm3
Polarizability: 11.88 ×10-24 cm3
Surface Tension: 27.1 dyne/cm
Enthalpy of Vaporization: 38.3 kJ/mol
Vapour Pressure: 4.73 mmHg at 25°C
The Cas Register Number of 2-Butenoyl chloride, 3-methyl- is 3350-78-5. The chemical synonyms of 2-Butenoyl chloride,3-methyl- (CAS NO.3350-78-5) are 2-Butenoyl chloride, 3-methyl- ; 3,3-Dimethylacrylyl chloride ; 3-methyl-2-butenoylchlorid ; 3-Methyl-2-butenoyl chloride ; 3-Methyl-but-2-enoyl chloride ; 3-Methylcrotonoyl chloride ; 3,3-Dimethylacryloyl chloride ; Senecioyl chloride .
The molecular structure of 2-Butenoyl chloride,3-methyl- (CAS NO.3350-78-5) is 
.
3,3-Dimethylacryloyl chloride Uses
2-Butenoyl chloride,3-methyl- (CAS NO.3350-78-5) is used as organic reagent and pharmaceutical intermediate.
3,3-Dimethylacryloyl chloride Safety Profile
Hazard Codes: 
C
Risk Statements: 14-34-36/37-10
R14: Reacts violently with water.
R34: Causes burns.
R36/37: Irritating to eyes and respiratory system.
R10: Flammable.
Safety Statements: 26-36/37/39-45-16
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S16: Keep away from sources of ignition.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2920 8/PG 2
WGK Germany: 3
F: 10-19
HazardClass: 3.2
PackingGroup: III
What can I do for you?
Get Best Price
