Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

2-Benzylaniline
Related Products

Hot Products

Basic Information Post buying leads Suppliers Cas Database
Name

2-Benzylaniline

 EINECS 248-806-3
CAS No. 28059-64-5 Density 1.071 g/cm3
PSA 26.02000 LogP 3.44080
Solubility N/A Melting Point 49-54 °C(lit.)
Formula C13H13N Boiling Point 311.727 °C at 760 mmHg
Molecular Weight 183.253 Flash Point 159.695 °C
Transport Information N/A Appearance N/A
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 28059-64-5 (2-Benzylaniline) Hazard Symbols IrritantXi
Synonyms

o-Toluidine,a-phenyl- (6CI,7CI,8CI);(2-Aminophenyl)phenylmethane;2-Benzylaniline;2-Benzylbenzenamine;o-Aminodiphenylmethane;o-Benzylaniline;

Article Data 49

2-Benzylaniline Synthetic route

5840-40-4

2-nitrodiphenylmethane

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
With hydrazine hydrate In methanol at 20℃; for 2h;100%
With hydrazine hydrate In methanol at 20℃; for 2h;100%
With hydrazine hydrate In methanol for 2h; Cooling with ice;97.3%
2835-77-0

(2-aminophenyl)(phenyl)methanone

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
With potassium hydroxide In water at 50℃; for 4h; Reagent/catalyst; Temperature;99.5%
With sodium In ethanol90%
With ethoxyethoxyethanol; hydrazine hydrate; potassium hydroxide at 200℃; under 10343.2 Torr; Wolff-Kishner Reduction; Sonication;82%
57479-65-9

2-amino-3'-chlorobenzophenone

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
With potassium hydroxide In water at 50℃; for 4h; Temperature;99.5%
719-59-5

2-Amino-5-chlorobenzophenone

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
Stage #1: 5-chloro-2-aminobenzophenone With hydrogen; triethylamine; palladium 10% on activated carbon In DMF (N,N-dimethyl-formamide) at 30 - 45℃; under 22502.3 Torr; for 3h;
Stage #2: With sodium hydroxide In DMF (N,N-dimethyl-formamide); water; toluene		94.6%
Stage #1: 5-chloro-2-aminobenzophenone With hydrogen; triethylamine; palladium 10% on activated carbon In tetrahydrofuran at 30 - 45℃; under 22502.3 Torr; for 1h;
Stage #2: With sodium hydroxide In tetrahydrofuran; water; toluene		93.9%
Stage #1: 5-chloro-2-aminobenzophenone With hydrogen; triethylamine; palladium 10% on activated carbon In 1-methyl-pyrrolidin-2-one at 30 - 45℃; under 22502.3 Torr; for 2h;
Stage #2: With sodium hydroxide In 1-methyl-pyrrolidin-2-one; water; toluene		92.9%
39093-44-2

2-aminobenzophenone hydrazone

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
With potassium hydroxide In 2-methoxy-ethanol at 60℃; Reagent/catalyst; Temperature; Solvent;93.4%
With potassium hydroxide In diethylene glycol
40182-20-5

2-benzylbenzamide

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
With sodium hypochlorite In water at 60℃; for 7h; Temperature;91.6%
17691-65-5

2-azidophenyl(phenyl)methane

A

92-81-9

acridine

B

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane Ambient temperature;A 89%
B 4%
With aluminium trichloride In dichloromethane Ambient temperature;A 89%
B 4%
2243-79-0

2-nitrobenzophenone

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
With potassium hydroxide; Raney Ni-Al alloy In water at 90℃; for 9h;84.5%

benzylzinc chloride-lithium chloride complex

615-36-1

2-bromoaniline

28059-64-5

2-benzylaniline

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; bis(acetylacetonate)nickel(II); triphenylphosphine In tetrahydrofuran at 60℃; for 0.5h; Inert atmosphere;75%
17691-65-5

2-azidophenyl(phenyl)methane

A

28059-64-5

2-benzylaniline

B

81734-63-6

o-(n-Butylamino)diphenylmethane

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran at -78 - 20℃; for 3h;A 72%
B 7%

2-Benzylaniline Specification

The Benzenamine,2-(phenylmethyl)-, with the CAS registry number 28059-64-5 and EINECS registry number 248-806-3, has the systematic name of 2-benzylaniline. It is a kind of organics, and should be stored in the dry and cool environment. And the molecular formula of the chemical is C13H13N.

The characteristics of Benzenamine,2-(phenylmethyl)- are as followings: (1)ACD/LogP: 2.93; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.9; (4)ACD/LogD (pH 7.4): 2.92; (5)ACD/BCF (pH 5.5): 92.7; (6)ACD/BCF (pH 7.4): 98.33; (7)ACD/KOC (pH 5.5): 875.53; (8)ACD/KOC (pH 7.4): 928.68; (9)#H bond acceptors: 1; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 3.24 Å2; (13)Index of Refraction: 1.616; (14)Molar Refractivity: 59.8 cm3; (15)Molar Volume: 171.1 cm3; (16)Polarizability: 23.7×10-24cm3; (17)Surface Tension: 45.3 dyne/cm; (18)Density: 1.07 g/cm3; (19)Flash Point: 159.7 °C; (20)Enthalpy of Vaporization: 55.27 kJ/mol; (21)Boiling Point: 311.7 °C at 760 mmHg; (22)Vapour Pressure: 0.000553 mmHg at 25°C.

Preparation of Benzenamine,2-(phenylmethyl)-: This chemical can be prepared by 2-amino-benzophenone. The reaction will need reagent Na, and the menstruum ethanol. And the yield is about 90%. 

Uses of Benzenamine,2-(phenylmethyl)-: It can react with 2,2-dimethyl-propionyl chloride to produce N-(2-benzyl-phenyl)-2,2-dimethyl-propionamide. This reaction will need reagent sodium carbonate, and the menstruum CH2Cl2. The reaction time is 3 hours with ambient temperature, and the yield is about 30%.   

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: c1(ccccc1)Cc2ccccc2N
(2)InChI: InChI=1/C13H13N/c14-13-9-5-4-8-12(13)10-11-6-2-1-3-7-11/h1-9H,10,14H2
(3)InChIKey: DWOBGCPUQNFAFB-UHFFFAOYAU

 

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 28059-64-5