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2,2-Dimethoxyethylamine
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  • Name 2,2-Dimethoxyethylamine
  • EINECS245-026-5
  • CAS No. 22483-09-6
  • Density0.944 g/cm3
  • PSA44.48000
  • LogP0.26430
  • Solubilitymiscible with water
  • Melting Point-78oC
  • FormulaC4H11NO2
  • Boiling Point133 °C at 760 mmHg
  • Molecular Weight105.137
  • Flash Point53.3 °C
  • Transport InformationUN 1993 3/PG 3
  • Appearanceclear colorless to pale yellow liquid
  • Safety26-36/37/39-45-16-36
  • Risk Codes10-34-36/37/38
  • Molecular Structure
    Molecular Structure of 22483-09-6 (2,2-Dimethoxyethylamine)
  • Hazard SymbolsCorrosiveC,FlammableF,IrritantXi
  • SynonymsCorrosiveC,FlammableF,IrritantXi
  • Article Data16

2,2-Dimethoxyethylamine Synthetic route

97-97-2

chloroacetaldehyde dimethyl acetal

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With ammonium hydroxide; carbon dioxide at 140℃; for 8h; Autoclave; Large scale;94.2%
With methanol; ammonia at 140℃;
With ammonia at 20 - 70℃; under 15001.5 Torr; for 20h; Temperature; Pressure; Autoclave;84.8 g
27328-34-3

2-(2,2-dimethoxyethyl)-1H-isoindole-1,3(2H)-dione

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With ethanolamine at 170 - 180℃;91%

allyl 2,2-dimethoxyethylcarbamate

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With tris(2,2'-bipyridine)nickel(II) tetrafluoroborate In tetrahydrofuran at 20℃; allyl carbamate cleavage; Electrochemical reaction; Zn/stainless steel couple electrodes; current intensity 60 mA; supporting electrolite: bis(trifluoromethylsulfonimide)Li;60%
7252-83-7

1-bromo-2,2-dimethoxyethane

A

56548-04-0

bis(dimethoxyethyl)amine

B

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With ethanol; ammonia at 140℃;
With ethanol; ammonia at 140℃; im Autoklaven;
5861-24-5

dimethoxy acetonitrile

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With cyclohexane; ammonia; nickel at 90℃; under 66195.7 Torr; Hydrogenation;
With ammonia; nickel In methanol
With ammonia; nickel
With ammonia; nickel
22483-16-5

C8H17NO2

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
In water at 35℃; Equilibrium constant;

Co(3+)*2(CCH3NO)2H(1-)*CH2CO2(2-)*(CH3O)2CHCH2NH2 = Co((CCH3NO)2H)2(CH2COO)(NH2CH2CH(OCH3)2)(1-)

778519-97-4

Co((CCH3NO)2H)2(CH2COO)H2O(1-)

B

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With KCl; H2O In water Kinetics; 25°C; not isolated, detected spectrophotometrically;

Co(3+)*2(CCH3NO)2H(1-)*CH(CH3)CO2(2-)*(CH3O)2CHCH2NH2 = Co((CCH3NO)2H)2(CH(CH3)COO)(NH2CH2CH(OCH3)2)(1-)

786578-25-4

Co((CCH3NO)2H)2(CH(CH3)COO)H2O(1-)

B

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With KCl; H2O In water Kinetics; 25°C; not isolated, detected spectrophotometrically;
81956-67-4

(carboxymethyl)(2,2-dimethoxyethylamine)bis(dimethylglyoximato)cobalt(III)

60193-28-4

(carboxymethyl)aquocobaloxime

B

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With KCl; H2O In water Kinetics; 25°C; not isolated, detected spectrophotometrically;
81956-81-2

(1-carboxyethyl)(2,2-dimethoxyethylamine)bis(dimethylglyoximato)cobalt(III)

778519-97-4

Co((CCH3NO)2H)2(CH2COO)H2O(1-)

B

22483-09-6

2,2-dimethoxyethylamine

Conditions
ConditionsYield
With KCl; H2O In water Kinetics; 25°C; not isolated, detected spectrophotometrically;

2,2-Dimethoxyethylamine Chemical Properties

Product Name: Aminoacetaldehyde dimethyl acetal (CAS NO.22483-09-6)


Molecular Formula: C4H11NO2
Molecular Weight: 105.14g/mol
Mol File: 22483-09-6.mol
EINECS: 245-026-5
Appearance: Clear colorless to pale yellow liquid
Boiling point: 135-139 °C 95 mm Hg(lit.)
Storage Temperature: Flammables area
Flash Point: 128 °F
Density: 0.965 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.417(lit.)
Surface Tension: 28.4 dyne/cm
Enthalpy of Vaporization: 37.05 kJ/mol
Vapour Pressure: 8.66 mmHg at 25°C
XLogP3-AA: -0.8
H-Bond Donor: 1
H-Bond Acceptor: 3
Structure Descriptors of Aminoacetaldehyde dimethyl acetal (CAS NO.22483-09-6):
IUPAC Name: 2,2-dimethoxyethanamine
Canonical SMILES: COC(CN)OC
InChI: InChI=1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3
InChIKey: QKWWDTYDYOFRJL-UHFFFAOYSA-N
Product Categories: Pharmaceutical Intermediates

2,2-Dimethoxyethylamine Safety Profile

Safety Information of Aminoacetaldehyde dimethyl acetal (CAS NO.22483-09-6):
Hazard Codes: CCorrosive,FFlammable,XiIrritant
Risk Statements: 10-34-36/37/38
R10:  Flammable
R34:  Causes burns  
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39-45-16-36
S16:  Keep away from sources of ignition - No smoking 
S26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice  
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
RIDADR: UN 1993 3/PG 3
WGK Germany: 2
Hazard Note: Flammable/Corrosive
HazardClass: 3
PackingGroup: III
HS Code: 29225000

2,2-Dimethoxyethylamine Specification

 2,2-Dimethoxyethylamine , its CAS NO. is 22483-09-6, the synonyms are Acetaldehyde,amino-, dimethyl acetal (6CI,8CI) ; Ethylamine, 2,2-dimethoxy- (8CI) ; 1-Amino-2,2-dimethoxyethane ; 2,2-Dimethoxyethanamine .

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