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Name |
1-Phenyl-1-propanol |
EINECS | 202-256-0 |
CAS No. | 93-54-9 | Density | 0.994 g/cm3 |
PSA | 20.23000 | LogP | 2.13000 |
Solubility | insoluble in water | Melting Point |
N/A |
Formula | C9H12O | Boiling Point | 219 °C at 760 mmHg |
Molecular Weight | 136.194 | Flash Point | 97.3 °C |
Transport Information | UN 2810 | Appearance | clear colorless liquid |
Safety | 23-24/25 | Risk Codes | 22 |
Molecular Structure | Hazard Symbols | Xn | |
Synonyms |
Benzylalcohol, a-ethyl- (8CI);(RS)-1-Phenylpropan-1-ol;(RS)-1-Phenylpropanol;1-Hydroxy-1-phenylpropane;1-Phenyl-1-hydroxypropane;1-Phenyl-n-propanol;1-Propanol, 1-phenyl-;Bilergon;Carbicol;Ejibil;Epatoxfen;Felicur;Felitrope;Fepar;Livonal;NSC 41708;Phenicol;Phenycholon;Phenylchol;SH 261;a-Ethylbenzenemethanol;a-Hydroxypropylbenzene; |
Article Data | 544 |
Conditions | Yield |
---|---|
With methylaluminum bis(2,6-di-tert-butylphenoxide) In diethyl ether; toluene at -78℃; for 2h; | 100% |
In diethyl ether at 0 - 20℃; | 87% |
Stage #1: ethylmagnesium bromide; benzaldehyde In tetrahydrofuran at 30℃; for 24h; Inert atmosphere; Stage #2: With water In tetrahydrofuran Inert atmosphere; | 73% |
Conditions | Yield |
---|---|
With potassium hydride; ditriptylethylborane In tetrahydrofuran for 0.0833333h; | 100% |
With zirconium dioxide hydrate; isopropyl alcohol at 130℃; for 0.5h; Meerwein-Ponndorf-Verley Reduction; | 100% |
With hydrogen In methanol at 40℃; for 24h; chemoselective reaction; | 100% |
Conditions | Yield |
---|---|
With C35H41ClFeIrPS; hydrogen; sodium methylate In tetrahydrofuran at 25℃; under 22502.3 Torr; for 2h; Reagent/catalyst; Autoclave; Inert atmosphere; | 100% |
With sodium tetrahydroborate; C11H18Cl2CoN2S; hydrogen In isopropyl alcohol at 100℃; under 37503.8 Torr; for 16h; Glovebox; Autoclave; | 97% |
With 1,1'-bis(diphenylphosphino)ferrocene; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; Butane-1,4-diol; potassium tert-butylate at 110℃; for 24h; Inert atmosphere; | 92% |
2-(1-phenyl-propoxy)-tetrahydro-pyran
1-Phenyl-1-propanol
Conditions | Yield |
---|---|
silica-supported prop-1-ylsulfonic acid In methanol | 99.6% |
With tetra-N-butylammonium tribromide In methanol at 20℃; for 1h; | 97% |
With tetra-N-butylammonium tribromide In methanol for 1.2h; | 97% |
With trichloroisocyanuric acid In methanol at 20℃; for 4h; | 92% |
Conditions | Yield |
---|---|
With (1R,2S)-2-aminomethyl-2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptane In hexane for 48h; | 99% |
With polystyrene bond triphenylphosphonium chloride In toluene at 0 - 23℃; Inert atmosphere; chemoselective reaction; | 99% |
With 15-crown-5; sodium iodide In toluene at 0 - 23℃; for 24h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique; | 99% |
Conditions | Yield |
---|---|
With hydrogen; TMSB; palladium In ethanol at 20℃; under 760 Torr; for 20h; | 98% |
With riboflavin tetrabutyrate; oxygen; hydrazine hydrate In acetonitrile at 30℃; under 760.051 Torr; for 30h; | 92% |
With oxygen; hydrazine hydrate; riboflavin 2’,3’,4’,5’-tetrabutanoate In acetonitrile at 25 - 30℃; for 30h; chemoselective reaction; | 92% |
Conditions | Yield |
---|---|
With titanium tetrachloride In dichloromethane at -78 - -30℃; Product distribution; further aldehydes and tetraalkylleads; reaction with mixed tetraalkylleads; other conditions; | 98% |
With titanium tetrachloride In dichloromethane at -78 - -30℃; | 98% |
With titanium tetrachloride In dichloromethane at -78 - -30℃; | 96% |
triethyl-butyl plumbane
benzaldehyde
A
1-Phenyl-1-propanol
B
1-Phenyl-1-pentanol
Conditions | Yield |
---|---|
With titanium tetrachloride In dichloromethane at -78 - -30℃; | A 98% B 1.7% |
1-phenyl-1-tert-butyldimethylsiloxypropane
1-Phenyl-1-propanol
Conditions | Yield |
---|---|
With tetra-N-butylammonium tribromide In methanol for 7h; | 98% |
With N-iodo-succinimide In methanol at 20℃; for 19h; | 95% |
With methanol at 20℃; for 3.33333h; | 93% |
sulfonic acid functionalized nanoporous silica In methanol at 35℃; for 12h; | 87% |
With tetrabutyl ammonium fluoride |
Conditions | Yield |
---|---|
In toluene for 0.166667h; Alkylation; reduction; Title compound not separated from byproducts.; | A 97% B 2% |
1. | orl-rat LD50:1600 mg/kg | ARZNAD Arzneimittel-Forschung. Drug Research. 12 (1962),347. | ||
2. | orl-mus LD50:500 mg/kg | AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. 116 (1958),154. | ||
3. | scu-mus LD50:700 mg/kg | AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. 116 (1958),154. |