Basic Information | Post buying leads | Suppliers | Cas Database |
Name |
1,6-Anhydro-beta-d-mannopyranose |
EINECS | 207-855-0 |
CAS No. | 14168-65-1 | Density | 1.689 g/cm3 |
PSA | 79.15000 | LogP | -2.17580 |
Solubility | N/A | Melting Point |
182-184 °C |
Formula | C6H10O5 | Boiling Point | 383.754 °C at 760 mmHg |
Molecular Weight | 162.142 | Flash Point | 185.888 °C |
Transport Information | N/A | Appearance | White crystalline solid |
Safety | 26-36 | Risk Codes | 20/21/22-36/37/38 |
Molecular Structure | Hazard Symbols | Xn,Xi | |
Synonyms |
Mannopyranose,1,6-anhydro-, b-D-(6CI,8CI);1,6-Anhydro-D-mannose;1,6-Anhydro-b-D-mannopyranose;1,6-Anhydromannose;Mannosan;NSC 226600; |
Article Data | 26 |
D-Mannose
mannosan
Conditions | Yield |
---|---|
With p-toluenesulfonyl chloride In pyridine for 4h; Ambient temperature; | 80% |
With pyridine; p-toluenesulfonyl chloride at 20℃; for 21h; Inert atmosphere; | 48.4% |
With toluene-4-sulfonic acid In N,N-dimethyl-formamide | 20% |
6-O-p-toluenesulfonyl-D-mannopyranose
mannosan
Conditions | Yield |
---|---|
NaOH In pyridine; sodium hydroxide for 1h; Ambient temperature; | 77% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In ethanol Ambient temperature; | |
With sodium hydride In N,N-dimethyl-formamide for 15h; Ambient temperature; | |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile for 0.5h; Ambient temperature; |
1,6-anhydro-2,3,4-tri-O-benzyl-β-D-mannopyranose
A
1,6-anhydro-3-O-benzoyl-β-D-mannopyranose
B
mannosan
Conditions | Yield |
---|---|
palladium on activated charcoal In isopropyl alcohol for 4h; Heating; | A 40% B n/a |
With isopropyl alcohol; palladium on activated charcoal for 4h; Heating; | A 40% B n/a |
2,3,4-tri-O-acetyl-1,6-anhydro-β-D-mannopyranose
mannosan
Conditions | Yield |
---|---|
With methanol; barium methoxide |
D-Mannose
mannosan
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid; benzene In N,N-dimethyl-formamide |
(1R,2S,6S,7R,8R)-7-Allyloxy-4-vinyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane
mannosan
Conditions | Yield |
---|---|
With sodium acetate; palladium dichloride In acetic acid at 20℃; for 24h; |
1,6-anhydro-2,3-O-isopropylidene-β-D-mannopyranose
mannosan
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In methanol for 30h; Heating; |
mannosan
Conditions | Yield |
---|---|
With sulfuric acid |
This chemical is called β-D-Mannopyranose, 1,6-anhydro-, and its systematic name is (1R,2S,3S,4S,5R)-6,8-dioxabicyclo[3.2.1]octane-2,3,4-triol (non-preferred name). With the molecular formula of C6H10O5, its molecular weight is 162.14. The CAS registry number of this chemical is 14168-65-1. Additionally, its product category is Carbohydrates & Derivatives.
Other characteristics of the β-D-Mannopyranose, 1,6-anhydro- can be summarised as followings: (1)ACD/LogP: -0.04; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.04; (4)ACD/LogD (pH 7.4): -0.04; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 22.6; (8)ACD/KOC (pH 7.4): 22.6; (9)#H bond acceptors: 5; (10)#H bond donors: 3; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 46.15 Å2; (13)Index of Refraction: 1.619; (14)Molar Refractivity: 33.7 cm3; (15)Molar Volume: 95.9 cm3; (16)Polarizability: 13.36×10-24cm3; (17)Surface Tension: 70.6 dyne/cm; (18)Density: 1.688 g/cm3; (19)Flash Point: 185.9 °C; (20)Enthalpy of Vaporization: 73.13 kJ/mol; (21)Boiling Point: 383.8 °C at 760 mmHg; (22)Vapour Pressure: 1.81E-07 mmHg at 25°C.
You can still convert the following datas into molecular structure:
1.SMILES: O[C@H]2[C@@H](O)[C@H](O)[C@@H]1O[C@H]2OC1
2.InChI: InChI=1/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2/t2-,3-,4+,5+,6-/m1/s1
3.InChIKey: TWNIBLMWSKIRAT-RWOPYEJCBN