Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
With trimethyl orthoformate at 40℃; under 6000480 Torr; for 8h; | 100% |
With chloranil In acetonitrile for 0.5h; Irradiation; | 99% |
With trimethyl orthoformate at 20℃; for 0.5h; | 98% |
Conditions | Yield |
---|---|
With tetra-N-butylammonium tribromide In methanol at 20℃; for 0.33h; | 99% |
Nafion-H In tetrachloromethane | 98% |
With lithium tetrafluoroborate In methanol for 0.333333h; Heating; | 98% |
Conditions | Yield |
---|---|
trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 3h; | 89% |
trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 3h; | 89% |
With trimethylsilyl trifluoromethanesulfonate |
methanol
heptanal
cyclohexanone
A
cycloxexanone dimethyl ketal
B
1,1-dimethoxyheptane
Conditions | Yield |
---|---|
With CoCl2 for 3.5h; Heating; | A n/a B 88% |
Conditions | Yield |
---|---|
With tetraethylammonium tosylate electrolysis (15 F/mol, 0.5 A); | 69% |
cyclohexanone
orthoformic acid triethyl ester
trimethyleneglycol
cycloxexanone dimethyl ketal
Conditions | Yield |
---|---|
Stage #1: cyclohexanone; orthoformic acid triethyl ester; trimethyleneglycol With zirconium(IV) chloride In dichloromethane at 20℃; for 1h; Stage #2: With sodium hydroxide | 55% |
Dimethoxymethane
1-(Trimethylsilyloxy)cyclohexene
A
cycloxexanone dimethyl ketal
B
2-(methoxymethyl)cyclohexanone
Conditions | Yield |
---|---|
With 2,6-di-tert-butyl-pyridine; trimethylsilyl trifluoromethanesulfonate In dichloromethane at 16℃; for 10h; | A 20% B 48% |
methanol
cyclohexanone
A
cycloxexanone dimethyl ketal
B
hexanedioic acid dimethyl ester
C
2-methoxycyclohex-2-en-1-one
Conditions | Yield |
---|---|
With cerium(IV) sulphate; oxygen at 50℃; for 8h; Oxidation; acetalization; | A 38% B 35% C 7% |
methanol
cyclohexanone
A
cycloxexanone dimethyl ketal
B
1-(hydroxymethyl)cyclohexanol
Conditions | Yield |
---|---|
With titanium(IV) dichlorodiisopropylate at 20℃; for 72h; UV-irradiation; Inert atmosphere; Overall yield = 38 %; | A 29% B 9% |
methanol
1-iodo-1-cyclohexene
A
cycloxexanone dimethyl ketal
B
1-methoxy-cyclohex-1-ene
C
cyclohexene
Conditions | Yield |
---|---|
With zinc at 40℃; for 10h; Irradiation; | A 8% B 65 % Chromat. C 27% |
With zinc Product distribution; Further Variations:; Reagents; Irradiation; sonication; |
The IUPAC name of Cyclohexane,1,1-dimethoxy- is 1,1-dimethoxycyclohexane. With the CAS registry number 933-40-4, it is also named as Cyclohexanone, dimethyl acetal. In addition, its molecular formula is C8H16O2 and molecular weight is 144.21.
The other characteristics of this product can be summarized as: (1)ACD/LogP: 1.30; (2)ACD/LogD (pH 5.5): 1.3; (3)ACD/LogD (pH 7.4): 1.3; (4)ACD/BCF (pH 5.5): 5.7; (5)ACD/BCF (pH 7.4): 5.7; (6)ACD/KOC (pH 5.5): 120.94; (7)ACD/KOC (pH 7.4): 120.94; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 2; (10)Polar Surface Area: 18.46Å2; (11)Index of Refraction: 1.435; (12)Molar Refractivity: 40.52 cm3; (13)Molar Volume: 155.2 cm3; (14)Polarizability: 16.06x10-24cm3; (15)Surface Tension: 28.2 dyne/cm; (16)Enthalpy of Vaporization: 38.25 kJ/mol; (17)Boiling Point: 162.3 °C at 760 mmHg; (18)Vapour Pressure: 2.84 mmHg at 25 °C.
Preparation of Cyclohexane,1,1-dimethoxy-: this chemical can be prepared by Cyclohexanone and Methanol.
This reaction needs I2. The reaction time is 1 hour. The yield is about 90%.
Uses of Cyclohexane,1,1-dimethoxy-: it can be used to produce 1-Methoxy-cyclohexene.
This reaction needs Benzoyl chloride and quinoline at temperature of 60 - 70 °C.
When you are using this chemical, please be cautious about it as the following: it is flammable. In use, it may form inflammable/explosive vapour-air mixture. When you are using it, please keep away from sources of ignition and use only in well ventilated areas.
You can still convert the following datas into molecular structure:
(1)SMILES: O(C)C1(OC)CCCCC1
(2)InChI: InChI=1/C8H16O2/c1-9-8(10-2)6-4-3-5-7-8/h3-7H2,1-2H3
(3)InChIKey: XPIJMQVLTXAGME-UHFFFAOYAO
(4)Std. InChI: InChI=1S/C8H16O2/c1-9-8(10-2)6-4-3-5-7-8/h3-7H2,1-2H3
(5)Std. InChIKey: XPIJMQVLTXAGME-UHFFFAOYSA-N