98088-49-4Relevant articles and documents
Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates
Hayashi, Hirohito,Kaga, Atsushi,Wang, Bin,Gagosz, Fabien,Chiba, Shunsuke
supporting information, p. 7535 - 7538 (2018/07/13)
A new protocol for the anti-Markovnikov hydrofunctionalization of alkenyl alcohol O-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. The benzyl group serves as a traceless hydrogen donor in the remote radical hydrogen atom transfer event during the process.
C-H bond functionalization via hydride transfer: Lewis acid catalyzed alkylation reactions by direct interamolecular coupling of sp3 C-H bonds and reactive alkenyl oxocarbenium intermediates
McQuaid, Kevin M.,Sames, Dalibor
supporting information; experimental part, p. 402 - 403 (2009/07/01)
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