95419-14-0

Basic information

• Product Name: Benzenemethanol, a-[[bis(1-methylethyl)amino]methyl]-
• CAS NO: 95419-14-0
• Molecular Formula: C14H23NO
• Molecular Weight: 221.343
• Mol File: 95419-14-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[[bis(1-methylethyl)amino]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[[bis(1-methylethyl)amino]methyl]-(95419-14-0)
• EPA Substance Registry System: Benzenemethanol, a-[[bis(1-methylethyl)amino]methyl]-(95419-14-0)

Safety Data

• Hazardous Substances Data: 95419-14-0(Hazardous Substances Data)

Upstream product

• 96-09-3 styrene oxide 
• 108-18-9 diisopropylamine 
• 100-42-5 styrene 
• 75-31-0 isopropylamine 

Downstream Products

• 92328-71-7 N,N-Diisopropyl-2-brom-2-phenyl-aethylamin 

Relevant articles and documents

Photoinduced Olefin Diamination with Alkylamines

Vicinal diamines are ubiquitous materials in organic and medicinal chemistry. The direct coupling of olefins and amines would be an ideal approach to construct these motifs. However, alkene diamination remains a long-standing challenge in organic synthesis, especially when using two different amine components. We report a general strategy for the direct and selective assembly of vicinal 1,2-diamines using readily available olefin and amine building blocks. This mild and straightforward approach involves in situ formation and photoinduced activation of N-chloroamines to give aminium radicals that enable efficient alkene aminochlorination. Owing to the ambiphilic nature of the β-chloroamines produced, conversion into tetra-alkyl aziridinium ions was possible, thus enabling diamination by regioselective ring-opening with primary or secondary amines. This strategy streamlines the preparation of vicinal diamines from multistep sequences to a single chemical transformation.

Diisopropoxyaluminium trifluoroacetate: A new promoter for aminolysis of epoxides

Aminolysis of symmetrical as well as unsymmetrical epoxides using various amines in the presence of diisopropoxyaluminium trifluoroacetate (DIPAT) as a new promoter gave 1,2-amino alcohols in excellent yields at room temperature with good to excellent selectivities.

Regioalternating Selectivity in the Metal Salt Catalyzed Aminolysis of Styrene Oxide

-