952-06-7

Basic information

• Product Name: DeoxyBenzoinOxime
• Synonyms: (1E)-1,2-Diphenylethanone Oxime;(E)-2-Phenylacetophenone Oxime;SC-66276;α-Phenylacetophenone oxime;Ethanone,1,2-diphenyl-, oxime;(1E)-1,2-diphenylethanone oxiMe (Parecoxib sodiuM inteMediate);2-Phenylacetophenone oxiMe;Benzyl phenyl ketoxime
• CAS NO: 952-06-7
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.25912
• EINECS: 206-641-4
• Product Categories: Aromatics
• Mol File: 952-06-7.mol
• Article Data: 60

Chemical Properties

• Melting Point: 98℃
• Boiling Point: 375.4°Cat760mmHg
• Flash Point: 238°C
• Appearance: /
• Density: 1.04±0.1 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 2.65E-06mmHg at 25°C
• Refractive Index: 1.562
• PKA: 11.07±0.11(Predicted)
• CAS DataBase Reference: DeoxyBenzoinOxime(CAS DataBase Reference)
• NIST Chemistry Reference: DeoxyBenzoinOxime(952-06-7)
• EPA Substance Registry System: DeoxyBenzoinOxime(952-06-7)

Safety Data

• Hazardous Substances Data: 952-06-7(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

InChI:InChI=1/C14H13NO/c16-15-14(13-9-5-2-6-10-13)11-12-7-3-1-4-8-12/h1-10,16H,11H2/b15-14+

Upstream product

• 5162-99-2 2,3-Diphenylthiirene 1,1-dioxide 
• 3638-64-0 1-nitroethylene 
• 71-43-2 benzene 
• 451-40-1 phenyl benzyl ketone 
• 64-17-5 ethanol 
• 7803-49-8 hydroxylamine 
• 60-29-7 diethyl ether 
• 28925-38-4 α,β-Dinitrostilbene 
• 140-29-4 phenylacetonitrile 
• 98-80-6 phenylboronic acid 
• 546-88-3 acetylhydroxamic acid 
• 588-59-0 stilbene 
• 501-65-5 diphenyl acetylene 
• 119-53-9 2-hydroxy-2-phenylacetophenone 

Downstream Products

• 621-06-7 2,N-diphenylacetamide 
• 25611-78-3 (R,S)-1,2-diphenylethylamine 
• 484-47-9 lophine 
• 451-40-1 phenyl benzyl ketone 
• 100-47-0 benzonitrile 
• 100-51-6 benzyl alcohol 
• 99466-32-7 5-(4-methylimidazolyl)-3,4-diphenylisoxazole 
• 130317-97-4 N-(1,2-diphenylethenyl)-P,P-diphenylphosphinic amide 
• 131202-52-3 Triphenyl-3,4,5 (amino-1' ethyl)-5 4H,5H-isoxazole 
• 161864-25-1 1,2-diphenylethanone O-(2-bromoethyl)oxime 
• 57807-58-6 2,3-diphenyl-1-vinyl-1H-pyrrole 
• 1485-70-7 N-benzylbenzamide 
• 65-85-0 benzoic acid 
• 24301-97-1 tetraphenyl-2,3,5,6 pyridine 

Relevant articles and documents

Visible-Light-Promoted [3 + 2] Cycloaddition of 2H-Azirines with Quinones: Access to Substituted Benzo[f]isoindole-4,9-diones

A visible-light-promoteded [3 + 2] cycloaddition reaction of 2H-azirines with quinones has been developed under mild reaction conditions. The reaction provides a general and efficient strategy for the synthesis of the benzo[f]isoindole-4,9-diones scaffold

Synthesis of 1-Benzyl-, 1-Alkoxyl-, and 1-Aminoisoquinolines via Rhodium(III)-Catalyzed Aryl C-H Activation and Alkyne Annulation

One-pot syntheses of 1-benzyl-, 1-Alkoxyl-, and 1-Alkylamino-isoquinolines through automatic directing group (DGauto)-Assisted, rhodium(III)-catalyzed aryl C-H activation and annulation with internal alkynes were developed. The reactions affording 1-benzylisoquinolines involve a cascade oximation of diarylacetylenes with hydroxylamine, forming aryl benzyl ketone oxime, and oxime-Assisted rhodium(III)-catalyzed aryl C-H activation and followed annulation with another molecule of diarylacetylene in a one-pot manner. The formation of 1-Alkoxyl/amino isoquinolines includes the addition of nucleophilic alcohols or amines to aryl nitriles, imine-Assisted rhodium-catalyzed aryl C-H activation, and subsequent alkyne annulation.

The organocatalytic enantiodivergent fluorination of β-ketodiaryl-phosphine oxides for the construction of carbon-fluorine quaternary stereocenters

Commercially available cinchona alkaloids that can catalyze the enantiodivergent fluorination of β-ketodiarylphosphine oxides were developed to construct carbon-fluorine quaternary stereocenters. This protocol features a wide scope of substrates and excellent enantioselectivities, and it is scalable.