929259-42-7

Basic information

• Product Name: C₁₄H₂₃NO₂Si
• Synonyms: C₁₄H₂₃NO₂Si
• CAS NO: 929259-42-7
• Molecular Weight: 265.428
• Mol File: 929259-42-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₃NO₂Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₃NO₂Si(929259-42-7)
• EPA Substance Registry System: C₁₄H₂₃NO₂Si(929259-42-7)

Safety Data

• Hazardous Substances Data: 929259-42-7(Hazardous Substances Data)

Upstream product

• 18406-24-1 1-(triethylsilyloxy)-4-methoxybenzene 
• 13959-92-7 benzyl triethylsilyl ether 
• 994-30-9 triethylsilyl chloride 
• 103-90-2 4-acetaminophenol 

Relevant articles and documents

Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates

The silylation of O-H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO2SiR3 are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.

A mild and highly efficient method for the preparation of silyl ethers using Fe(HSO4)3/Et3N by chlorosilanes

Avery efficient and mild procedure for preparation of silyl ethers from benzylic, allylic, propargilic alcohols, phenols, naphtoles and some of phenolic drugs with trimethylsilylchloride (TMSCl), triethylsilylchloride (TESCl) and t-buthyldimethylsilyl chloride (TDSCl) ethers in the presence of Fe(HSO 4)3/Et3N in roomtemperature in excellent yields is reported. This procedure also allows the excellent selectivity for silylation of alcohols and phenols.