91190-65-7

Basic information

• Product Name: Benzene, 1,1'-(1-propenylidene)bis[2,4,6-trimethyl-
• CAS NO: 91190-65-7
• Molecular Formula: C21H26
• Molecular Weight: 278.437
• Mol File: 91190-65-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-propenylidene)bis[2,4,6-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-propenylidene)bis[2,4,6-trimethyl-(91190-65-7)
• EPA Substance Registry System: Benzene, 1,1'-(1-propenylidene)bis[2,4,6-trimethyl-(91190-65-7)

Safety Data

• Hazardous Substances Data: 91190-65-7(Hazardous Substances Data)

Upstream product

• 802294-64-0 propionic acid 
• 108-67-8 1,3,5-trimethyl-benzene 
• 79-03-8 propionyl chloride 
• 2040-15-5 2',4',6'-trimethylpropiophenone 
• 86119-84-8 phosphoric acid 

Downstream Products

• 96040-92-5 1,1-dimesitylacetone 

Relevant articles and documents

An efficient bismuth(III) chloride-catalyzed synthesis of 1,1-di-arylalkenes via Friedel-Crafts reaction of acyl chloride or vinyl chloride with arenes

In the presence of catalytic amount of bismuth(III) chloride, the reactions of acyl chlorides or vinyl chlorides with arenes afforded 1,1-diarylalkenes in 25-82% isolated yield. In the case of the reaction of acyl chlorides with arenes, the procedure includes an initial Friedel-Crafts acylation, subsequent formation of vinyl chlorides and final Friedel-Crafts-type vinylation of another arene molecule with vinyl chloride. This paper reports the first Lewis acid-catalyzed cleavage of the C-Cl bond of vinyl chloride and its application in the synthesis of multiply subtituted alkenes.