89902-44-3Relevant articles and documents
Enantiopure sulfoximines-catalyzed 1, 4-additions to 2-en-ketone
Zhao, Hongwei,Han, Hui,Yang, Hengquan,wang, Li
, p. 210 - 213 (2018/06/26)
An efficient chiral catalyst procedure for the preparation of β-chiral ketone via the 1, 4-additions reaction of 2-en-ketone has been developed using enantiopure sulfoximines modified with functional groups as ligands. The carefully design and synthesized
An unexpected cyclization reaction of tert-butyl o-trimethylsilylphenyl sulfoximine
Schmidt, Joerg Christoph,Adiwidjaja, Gunadi,Schaumann, Ernst
, p. 104 - 109 (2013/09/24)
An efficient one-pot synthesis of the title compound 5 starting from methyl phenyl sulfoximine is described. On attempted iododesilylation of this compound using iodine chloride, one methyl group on the silicon atom is formally replaced by the imino nitrogen to give a derivative 8 of the novel heterocyclic system 1,3,2-benzothiasilazole. ARKAT-USA, Inc.
Ortho-Lithiation of S-tert-butyl-S-phenylsulfoximines. New route to enantiopure sulfinamides via a de-tert-butylation reaction
Gaillard, Stéphane,Papamica?l, Cyril,Dupas, Georges,Marsais, Francis,Levacher, Vincent
, p. 8138 - 8147 (2007/10/03)
The sulfoximine group proved to be an excellent ortho-directing group in lithiation reactions. Several electrophiles were used to afford the corresponding ortho-functionalized aryl sulfoximines in good yields. The use of prochiral electrophiles lead to mo