89488-57-3

Basic information

• Product Name: 1,4-DIIODO-2-NITRO-BENZENE
• Synonyms: 1,4-DIIODO-2-NITRO-BENZENE;Benzene, 1,4-diiodo-2-nitro-
• CAS NO: 89488-57-3
• Molecular Formula: C₆H₃I₂NO₂
• Molecular Weight: 374.90246
• Mol File: 89488-57-3.mol
• Article Data: 4

Chemical Properties

• Melting Point: 109-110℃
• Boiling Point: 354.675 °C at 760 mmHg
• Flash Point: 168.302 °C
• Appearance: /
• Density: 2.578±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 6.74E-05mmHg at 25°C
• Refractive Index: 1.739
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• CAS DataBase Reference: 1,4-DIIODO-2-NITRO-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-DIIODO-2-NITRO-BENZENE(89488-57-3)
• EPA Substance Registry System: 1,4-DIIODO-2-NITRO-BENZENE(89488-57-3)

Safety Data

• Hazardous Substances Data: 89488-57-3(Hazardous Substances Data)

Usage

General Description

1,4-DIIODO-2-NITRO-BENZENE is a chemical compound with the molecular formula C6H3I2NO2. It is a toxic and potentially harmful substance that is used in the production of pharmaceuticals and organic compounds. It is a pale yellow crystalline solid with a strong odor and is insoluble in water. The compound is classified as a nitro compound, which means it contains a nitro group (-NO2) that is bonded to a benzene ring. It is important to handle 1,4-DIIODO-2-NITRO-BENZENE with caution and follow proper safety protocols when working with this chemical.

InChI:InChI=1/C6H3I2NO2/c7-4-1-2-5(8)6(3-4)9(10)11/h1-3H

Upstream product

• 99-09-2 3-nitro-aniline 
• 20691-72-9 4-iodo-2-nitroaniline 
• 105752-04-3 3-nitro-4-iodoaniline 
• 5307-14-2 2-nitro-1,4-phenylenediamine 
• 88-74-4 2-nitro-aniline 

Downstream Products

• 546112-66-7 2-nitro-1,4-bis(trimethylsilanylethynyl)benzene 

Relevant articles and documents

Regioselective Iodine/Zinc Exchange for the Selective Functionalization of Polyiodinated Arenes and Heterocycles in Toluene

Regioselective I/Zn-exchange reactions were performed on polyiodinated arenes or heterocycles within 20 minutes at 0-25 °C using the bimetallic combination pTol2Zn2LiOR [R = (CH2)2N(Me)(CH2)2NMe2] in toluene. The resulting diaryl- or diheteroarylzincs reacted well with allylic bromides and acyl chlorides to provide functionalized (hetero)- aryl iodides in good yields.

Synthesis of functionalized nitroarylmagnesium halides via an iodine-magnesium exchange

(Chemical Equation Presented) Various nitro-substituted aryl and heteroaryl iodides undergo an iodine-magnesium exchange reaction when treated with PhMgCl leading to nitro-containing magnesium organometallics. These Grignard reagents display an excellent stability at temperatures below -40°C and do not undergo electron-transfer reactions. They react as expected with various electrophiles.