87802-98-0

Basic information

• Product Name: 3-Cyclohexene-1-carboxylic acid, 5-[(methoxycarbonyl)oxy]-, methyl ester, (1R,5R)-rel-
• CAS NO: 87802-98-0
• Molecular Formula: C10H14O5
• Molecular Weight: 214.218
• Mol File: 87802-98-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexene-1-carboxylic acid, 5-[(methoxycarbonyl)oxy]-, methyl ester, (1R,5R)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxylic acid, 5-[(methoxycarbonyl)oxy]-, methyl ester, (1R,5R)-rel-(87802-98-0)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxylic acid, 5-[(methoxycarbonyl)oxy]-, methyl ester, (1R,5R)-rel-(87802-98-0)

Safety Data

• Hazardous Substances Data: 87802-98-0(Hazardous Substances Data)

Usage

General Description

The chemical "3-Cyclohexene-1-carboxylic acid, 5-[(methoxycarbonyl)oxy]-, methyl ester, (1R,5R)-rel-" is a specific stereoisomer of a methyl ester of a carboxylic acid derivative that contains a cyclohexene ring. This chemical is a compound with potential applications in various fields, including pharmaceuticals, agrochemicals, and materials science. The (1R,5R)-rel- configuration indicates that the stereochemistry of the molecule is specific, and it could have implications for its reactivity and biological activity. Further research and testing are likely needed to fully understand the properties and potential uses of this chemical compound.

Upstream product

• 54911-89-6 cis-methyl 5-hydroxycyclohex-3-enecarboxylate 
• 79-22-1 methyl chloroformate 
• 4771-80-6 1,2,5,6-tetrahydrobenzoic acid 
• 19914-92-2 (+/-)-4-iodo-6-oxabicyclo[3.2.1]octan-7-one 
• 4720-83-6 6-oxabicyclo<3.2.1>-oct-3-en-7-one 
• 26114-87-4 cis-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-ol 
• 493-72-1 5-phenyl-cyclohexane-1,3-dione 

Downstream Products

• 64841-68-5 methyl cis-6-(bis(methoxycarbonyl)methyl)cyclohexen-4-carboxylate 
• 136892-38-1 (±)-methyl 3-(1SR, 3SR)-(bis(methoxycarbonyl)methyl)-4-cyclohexenecarboxylate 
• 104713-41-9 2-((1R,5R)-5-Methoxycarbonyl-cyclohex-2-enyl)-malonic acid dimethyl ester 
• 120990-27-4 cis-3-methoxycarbonyl-2-cyclohexenyl azide 
• 74866-40-3 methyl (Z)-5-(phenylsulfonyl)-3-cyclohexene-1-carboxylate 
• 7605-57-4 methyl (1R,5S)-5-methylcyclohex-3-enecarboxylate 
• 7605-57-4 methyl cis-5-methylcyclohex-3-enecarboxylate 
• 1101861-61-3 (1R,5R)-methyl 5-(1-(2-nitrophenylsulfonyl)-2-(propan-2-ylidene)hydrazinyl)cyclohex-3-enecarboxylate 
• 305805-56-5 cis-5-methoxycarbonyl-3-nitromethylcyclohexene 

Relevant articles and documents

Asymmetric palladium-catalyzed allylic alkylation using dialkylzinc reagents: A remarkable ligand effect

A serendipitously discovered palladium-catalyzed asymmetric allylic alkylation reaction with diorganozinc reagents, which displays broad functional group compatibility, is reported. This novel transformation hinges on a remarkable ligand effect which overrides the standard "umpolung" reactivity of allyl-palladium intermediates in the presence of dialkylzincs. Owing to its mild conditions, enantioselective allylic alkylations of racemic allylic electrophiles are possible in the presence of sensitive functional groups. Umpole-me-not: A serendipitously discovered palladium-catalyzed asymmetric allylic alkylation reaction with diorganozinc reagents displays broad functional group compatibility. This novel transformation hinges on a remarkable ligand effect which overrides the standard "umpolung" reactivity of allyl-palladium intermediates in the presence of dialkylzinc compounds.