876928-77-7Relevant articles and documents
Monomeric and aggregation emissions of tetraphenylethene in a photo-switchable polymer controlled by cyclization of diarylethene and solvent conditions
Singh, Ravinder,Wu, Hsin-Yen,Kumar Dwivedi, Atul,Singh, Ashutosh,Lin, Chien-Min,Raghunath, Putikam,Lin, Ming-Chang,Wu, Tung-Kung,Wei, Kung-Hwa,Lin, Hong-Cheu
, p. 9952 - 9962 (2017)
A novel photo-switchable polymer P-PHT containing diarylethene (DAE) and tetraphenylethene (TPE) moieties and a triazole linker in the repeating unit was synthesized to study the aggregation-induced emission (AIE) behaviour of TPE with both the open and closed forms of DAE in P-PHT with high water contents. The photo-switching phenomena of DAE (from open to closed forms under UV-irradiation) in P-PHT were prominent in organic solvent (THF), high water contents (at 90% H2O) and acidic conditions. Upon UV-irradiation of P-PHT at 90% water content, the AIE of TPE was completely quenched via an energy transfer event from TPE to cyclized DAE. Interestingly, the rare monomeric emission of TPE was first discovered by the photo-cyclization of DAE in P-PHT compared with the AIE behaviour of TPE with the open form of DAE in P-PHT with AIE favourable conditions of high water content (90% H2O) and acidic conditions.
Diarylethene type photochromic insecticidal compound and preparation method and purpose thereof
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, (2017/06/20)
The invention relates to a diarylethene type photochromic insecticidal compound and a preparation method and a purpose thereof. Specifically, the invention discloses a compound as shown in formula (A) or an optical isomer or a cis-trans-isomer thereof, or an agricultural pharmaceutically acceptable salt, and the definitions of substituent groups are as stated in the description. The invention also discloses the preparation method and the purpose of the compound. The formula (A) is shown in the description.