858467-52-4

Basic information

• Product Name: 1,2-dimethyl-4-(2-nitrovinyl)benzene
• Synonyms: 1,2-dimethyl-4-(2-nitrovinyl)benzene
• CAS NO: 858467-52-4
• Molecular Weight: 177.203
• Mol File: 858467-52-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-dimethyl-4-(2-nitrovinyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-dimethyl-4-(2-nitrovinyl)benzene(858467-52-4)
• EPA Substance Registry System: 1,2-dimethyl-4-(2-nitrovinyl)benzene(858467-52-4)

Safety Data

• Hazardous Substances Data: 858467-52-4(Hazardous Substances Data)

Upstream product

• 854179-33-2 1-(3,4-dimethylphenyl)-2-nitroethan-1-ol 
• 5973-71-7 3,4-dimethylbenzaldehyde 

Downstream Products

• 1355334-03-0 2-(3,4-dimethylphenyl)-3-nitroimidazo[1,2-a]pyridine 
• 1382997-61-6 (1S,5S,6R,7S)-6-(3,4-dimethylphenyl)-1-hydroxy-7-nitrobicyclo[3.2.1]octan-8-one 
• 1313489-20-1 (S)-2-((R)-1-(3,4-dimethylphenyl)-2-nitroethyl)cyclohexanone 
• 1370286-07-9 (S)-4-[(S)-1-(3,4-dimethylphenyl)-2-nitroethyl]-2-(ethylthio)-4-isopropylthiazol-5(4H)-one 
• 1415352-28-1 (S)-methyl 1-acetyl-2-((S)-1-(3,4-dimethylphenyl)-2-nitroethyl)-3-oxoindoline-2-carboxylate 
• 1448632-14-1 (2'R,3'S,4'S,5'S)-1-benzyl-3'-(3,4-dimethylphenyl)-4'-nitro-5'-phenylspiro[indoline-3,2'-pyrrolidin]-2-one 
• 1459775-46-2 3-(3,4-dimethylphenyl)quinolin-2(1H)-one 
• 60-35-5 acetamide 

Relevant articles and documents

Metal-free ring expansion of indoles with nitroalkenes: A simple, modular approach to 3-substituted 2-quinolones

3-Substituted 2-quinolones are obtained via a novel metal-free transannulation reaction of 2-nitroolefins with 2-substituted indoles in polyphosphoric acid. This acid-mediated cascade transformation operates via the ANRORC (Addition of Nucleophile, Ring Opening, and Ring Closure) mechanism and can be used in combination with the Fisher indole synthesis to offer a practical three-component hetero-annulation approach to 2-quinolones from arylhydrazines, 2-nitroalkenes, and acetophenone. An alternative entry to this chemistry employing the alkylation of electron-rich arenes and hetarenes with 1-(2-indolyl)-2-nitroalkene has also been demonstrated.