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849921-25-1

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  • Ruthenium, dichloro[m-[(2S)-1-[(4S)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl-kN3]-2-(diphenylphosphino-kP)ferrocene]]-, (TB-5-13)- (9CI)

    Cas No: 849921-25-1

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849921-25-1 Usage

Description

(R)-2-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-4-ISOPROPYL-2-OXAZOLINE TRIPHENYLPHOSPHINE RUTHENIUM(II) CHLORIDE COMPLEX is a sophisticated organometallic compound that features a ruthenium(II) center coordinated to a unique ligand system. This complex is characterized by its chiral oxazoline backbone, which is adorned with a diphenylphosphino ferrocenyl group and a triphenylphosphine moiety. The presence of these functional groups endows the complex with distinctive catalytic properties, making it a valuable asset in various chemical transformations.

Uses

Used in the field of Asymmetric Catalysis:
(R)-2-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-4-ISOPROPYL-2-OXAZOLINE TRIPHENYLPHOSPHINE RUTHENIUM(II) CHLORIDE COMPLEX is used as a catalyst for the oxidative kinetic resolution of racemic alcohols. Its chiral environment and electronic properties enable the selective transformation of prochiral substrates into their enantioenriched counterparts, which is crucial for the synthesis of biologically active compounds and pharmaceuticals.
Used in the field of Hydrogenation Reactions:
This ruthenium complex is also employed as a catalyst for the highly enantioselective transfer hydrogenation of ketones. The process involves the reduction of ketones to their corresponding alcohols with excellent selectivity, which is pivotal for the production of enantiomerically pure compounds in the pharmaceutical and agrochemical industries.
Used in the field of Alcohol Resolution:
(R)-2-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-4-ISOPROPYL-2-OXAZOLINE TRIPHENYLPHOSPHINE RUTHENIUM(II) CHLORIDE COMPLEX is utilized in the oxidative kinetic resolution of alcohols. This method allows for the differentiation and conversion of enantiomers, providing an efficient route to access both enantiomers of a target molecule from a single racemic starting material.
Used in the field of Silicon-Hydrogen Chemistry:
The complex serves as a catalyst for the asymmetric hydrosilylation of ketones and imines. This reaction is significant for the formation of carbon-silicon bonds and the synthesis of organosilicon compounds, which have wide-ranging applications in materials science, polymer chemistry, and as precursors for pharmaceuticals.

Check Digit Verification of cas no

The CAS Registry Mumber 849921-25-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,4,9,9,2 and 1 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 849921-25:
(8*8)+(7*4)+(6*9)+(5*9)+(4*2)+(3*1)+(2*2)+(1*5)=211
211 % 10 = 1
So 849921-25-1 is a valid CAS Registry Number.

849921-25-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (+)-Dichloro[(4R)-4-(i-propyl)-2-{(R)-2-(diphenylphosphino)ferrocenyl}oxazoline](triphenylphosphine)ruthenium(II)

1.2 Other means of identification

Product number -
Other names NAUD CATALYST SK-N003-1Z

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:849921-25-1 SDS

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