80685-35-4

Basic information

• Product Name: PhHgSC₆H₄-2-NMe₂
• CAS NO: 80685-35-4
• Molecular Weight: 429.936
• Mol File: 80685-35-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: PhHgSC₆H₄-2-NMe₂(CAS DataBase Reference)
• NIST Chemistry Reference: PhHgSC₆H₄-2-NMe₂(80685-35-4)
• EPA Substance Registry System: PhHgSC₆H₄-2-NMe₂(80685-35-4)

Safety Data

• Hazardous Substances Data: 80685-35-4(Hazardous Substances Data)

Upstream product

• 18087-24-6 2-dimethylaminothiophenol 
• 100-57-2 phenylmercuric hydroxide 

Relevant articles and documents

AN X-RAY STRUCTURAL STUDY OF NONVALENCE INTERACTIONS AND COORDINATION IN ORGANOMETALLIC COMPOUNDS. XX. THE CRYSTAL STRUCTURE OF PHENYLMERCURY 2-DIMETHYLAMINOTHIOPHENOLATE

The structure of phenylmercury 2-dimethylaminothiophenolate has been determined by x-ray diffraction (R = 0.0277 from 3227 reflections).The mercury atom has the typical linear configuration of the valence bonds, which have their usual lengths, Hg-C 2.076(6) and Hg-S 2.365(2) Angstroem.At the same time, for the observed conformation of the molecule, the Hg atom approaches the N atom of the dimethylamino-group to a distance of 2.657(6) Angstroem, corresponding to a secondary bond.The nitrogen atom has a pyramidal bond configuration, and its unshared electron pair is oriented towards the mercury atom.The presence of the secondary bond Hg...N does not lead to significant bending of the S-Hg-N unit (the angle at the Hg atom is 178.0(2) deg).