783-08-4Relevant articles and documents
Controlling Proton-Coupled Electron Transfer in Bioinspired Artificial Photosynthetic Relays
Odella, Emmanuel,Mora, S. Jimena,Wadsworth, Brian L.,Huynh, Mioy T.,Goings, Joshua J.,Liddell, Paul A.,Groy, Thomas L.,Gervaldo, Miguel,Sereno, Leónides E.,Gust, Devens,Moore, Thomas A.,Moore, Gary F.,Hammes-Schiffer, Sharon,Moore, Ana L.
, p. 15450 - 15460 (2018)
Bioinspired constructs consisting of benzimidazole-phenol moieties bearing N-phenylimines as proton-accepting substituents have been designed to mimic the H-bond network associated with the TyrZ-His190 redox relay in photosystem II. These compo
Method for preparing asymmetric imine or asymmetric secondary amine compound through photocatalysis
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Paragraph 0029-0034; 0037-0038, (2022/01/10)
The invention relates to a method for preparing asymmetric imine or asymmetric secondary amine compounds through photocatalysis. According to the method, under the conditions of illumination and inert gas, different types of photocatalysts supported by cocatalysts are selected, so that an aromatic alcohol compound and an aromatic amino compound can react to obtain the asymmetric imine compound or the asymmetric secondary amine compound. The method can be used for replacing the existing mature organic synthesis process, is mild in condition and high in selectivity, has universality and is suitable for industrial production.
Integrated Flow Synthesis of α-Amino Acids byIn SituGeneration of Aldimines and Subsequent Electrochemical Carboxylation
Naito, Yuki,Nakamura, Yuto,Shida, Naoki,Senboku, Hisanori,Tanaka, Kenta,Atobe, Mahito
, p. 15953 - 15960 (2021/07/20)
The synthesis of α-amino acids was carried out in a continuous flow system. In this system, aldimines were efficiently generatedin situvia the dehydration-condensation of aldehydes with anilines in a desiccant bed column filled with 4 ? molecular sieves d