73882-47-0Relevant articles and documents
Regioselective synthesis of multisubstituted pyrazoles via cyclocondensation of β-thioalkyl-α,β-unsaturated ketones with hydrazines
Jin, Weiwei,Yu, Haifeng,Yu, Zhengkun
experimental part, p. 5884 - 5887 (2011/12/02)
Multisubstituted pyrazoles were efficiently synthesized by cyclocondensation of β-thioalkyl-α,β-unsaturated ketones with hydrazines under relatively mild conditions. A one-pot synthetic protocol through tandem Liebeskind-Srogl cross-coupling/cyclocondensation using a-oxo ketene dithioacetals as the starting materials was also realized for the same purpose.
Porphyrins with four azole substituents in meso positions: X-ray crystal structure of meso-tetrakis-(1-benzylpyrazol-4-yl)-porphyrin at 200 K
Werner, Andreas,Sanchez-Migallon, Ana,Fruchier, Alain,Elguero, Jose,Fernandez-Castano, Cristina,Foces-Foces, Concepcion
, p. 4779 - 4800 (2007/10/02)
Several new porphyrins have been prepared in improved yields using an established method which was adapted to formylpyrazoles bearing on the pyrazole N1-nitrogen protective groups. The deprotection of N-para-methoxybenzyl and SEM protected meso