73821-89-3Relevant articles and documents
LEWISSAEURE-KATALYSIERTE SYNTHESEN VON DI- UND TRI-SACCHARID-SEQUENZEN DER O- UND N-GLYCOPROTEINE, ANWENDUNG VON TRIMETHYLSILYLTRIFLUOROMETHANESULFONAT
Paulsen, Hans,Paal, Michael
, p. 53 - 70 (2007/10/02)
In the presence of trimethylsilyltrifluoromethanesulfonate as Lewis acid catalyst, β-acetates reacted, as glycosyl donors and with neighboring-group participation, with secondary hydroxyl groups of saccharides having low reactivity to give β-glycosidicall
SYNTHESEBLOCK β-D-GaL(13)-D-GaLNAc ZUR SELEKTIV-SIMULTANEN ANKUEPFUNG AN PEPTIDE ZU O-GLYCOPEPTIDEN
Paulsen, Hans,Paal, Michael,Schultz, Michael
, p. 1759 - 1762 (2007/10/02)
The development of a block of α-D-Gal(13)-D-GalNAc is described which allows a simultaneously selective α-glycosidic coupling of some units to the OH-groups of hydroxy amino acids containing peptides to O-glycopeptides.