7367-85-3

Basic information

• Product Name: methyl (E)-2-decenoate
• Synonyms: methyl (E)-2-decenoate;(E)-2-Decenoic acid methyl ester;Einecs 230-916-8
• CAS NO: 7367-85-3
• Molecular Formula: C₁₁H₂₀O₂
• Molecular Weight: 184.2753
• EINECS: 230-916-8
• Mol File: 7367-85-3.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 235.7°Cat760mmHg
• Flash Point: 106.1°C
• Appearance: /
• Density: 0.889g/cm³
• CAS DataBase Reference: methyl (E)-2-decenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (E)-2-decenoate(7367-85-3)
• EPA Substance Registry System: methyl (E)-2-decenoate(7367-85-3)

Safety Data

• Hazardous Substances Data: 7367-85-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 24, p. 4405, 1983 DOI: 10.1016/S0040-4039(00)85909-2

InChI:InChI=1S/C11H20O2/c1-3-4-5-6-7-8-9-10-11(12)13-2/h9-10H,3-8H2,1-2H3/b10-9+

Upstream product

• 35060-79-8 Nonadien-1,4-carbonsaeure-1-methylester 
• 67-56-1 methanol 
• 110232-46-7 (E)-dec-2-enoyl chloride 
• 124-13-0 Octanal 
• 219617-17-1 methyl (diphenoxyphosphoryl)acetate 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 111-87-5 octanol 
• 118793-68-3 methyl (E)-dec-2-en-4-ynoate 
• 628-71-7 1-Heptyne 
• 3913-81-3 (E)-2-decenal 
• 1067-74-9 Methyl diethylphosphonoacetate 
• 334-49-6 trans-2-decenoic acid 
• 592-76-7 1-Heptene 
• 344902-95-0 (E)-4-Benzenesulfonyl-2-diethylamino-undec-2-enenitrile 

Downstream Products

• 334-49-6 trans-2-decenoic acid 
• 18409-18-2 (E)-2-decenol 
• 351340-41-5 (3R,4R)-1-Benzyl-3-benzyloxy-4-[(1S,2S)-1,2-bis-(tert-butyl-dimethyl-silanyloxy)-nonyl]-azetidin-2-one 
• 351340-29-9 (3R,4S)-1-Benzyl-3-benzyloxy-4-((1S,2S)-1,2-dihydroxy-nonyl)-azetidin-2-one 
• 351340-74-4 Benzyl-[(2S,3S)-2,3-bis-(tert-butyl-dimethyl-silanyloxy)-dec-(E)-ylidene]-amine 
• 351340-39-1 (3R,4S)-1-Benzyl-3-benzyloxy-4-((4S,5S)-5-heptyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-azetidin-2-one 
• 351340-24-4 (3R,4S)-1-Benzyl-3-benzyloxy-4-((E)-non-1-enyl)-azetidin-2-one 
• 351340-71-1 Benzyl-[1-((4S,5S)-5-heptyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-meth-(E)-ylidene]-amine 
• 144398-20-9 Acaterin 
• 71271-24-4 2-Hydroxycaprinsaeure-methylester 
• 141045-75-2 Methyl 3-(N-Benzylamino)decanoate 
• 60139-03-9 methyl 6-heptyl-4-hydroxy-2-oxocyclohex-3-enecarboxylate 

Relevant articles and documents

Expansion of substrate scope for nitroxyl radical/copper-catalyzed aerobic oxidation of primary alcohols: A guideline for catalyst selection

Four distinctive sets of optimum nitroxyl radical/copper salt/additive catalyst combinations have been identified for accommodating the aerobic oxidation of various types of primary alcohols to their corresponding aldehydes. Interestingly, less nucleophilic catalysts exhibited higher catalytic activities for the oxidation of particular primary allylic and propargylic alcohols to give α,β-unsaturated aldehydes that function as competent Michael acceptors. The optimum conditions identified herein were successful in the oxidation of various types of primary alcohols, including unprotected amino alcohols and divalent-sulfur-containing alcohols in good-to-high yields. Moreover, N-protected alaninol, an inefficient substrate in the nitroxyl radical/ copper-catalyzed aerobic oxidation, was oxidized in good yield. On the basis of the optimization results, a guideline for catalyst selection has been established.

The Catalytic Asymmetric Mukaiyama–Michael Reaction of Silyl Ketene Acetals with α,β-Unsaturated Methyl Esters

α,β-Unsaturated esters are readily available but challenging substrates to activate in asymmetric catalysis. We now describe an efficient, general, and highly enantioselective Mukaiyama–Michael reaction of silyl ketene acetals with α,β-unsaturated methyl esters that is catalyzed by a silylium imidodiphosphorimidate (IDPi) Lewis acid.

Agent having neurotrophic factor-like activity

The present invention provides a pharmaceutical agent having high safety and a neurotrophic factor-like activity, which contains, as an active ingredient, any one compound included in fatty acids each having 8 carbon atoms (C8) or having 10 carbon atoms (C10) to 12 carbon atoms (C12) or fatty acid esters thereof, such as 3,7-dimethyloctanoic acid ethyl ester, geranicacidethyl ester, and the like, eachof whichhas 8 carbonatoms (C8), decanoic acid methyl ester, trans-2-decenoic acid, trans-2-decenoic acid methyl ester, trans-2-decenoic acid ethyl ester, trans-2-decenoic acid-2-decenyl ester, trans-2-decenoic acid cyclohexyl ester, trans-2-decenoic acid isopropyl ester, trans-3-decenoic acid methyl ester, trans-9-decenoic acid methyl ester, and the like, each of which has 10 carbon atoms (C10), trans-10-undecenoic acid methyl ester, trans-10-undecenoic acid ethyl ester, and the like, each of which has 11 carbon atoms (C11), and dodecanoic acid, and the like, each of which has 12 carbon atoms (C12), or salts thereof or prodrugs thereof.