73604-52-1Relevant articles and documents
Investigating a Redox Active Samarium Complex in Catalytic Reactions
Kaufmann, Sebastian,Roesky, Peter W.
supporting information, p. 2899 - 2905 (2021/06/27)
Herein the synthesis of a new ethynyl ferrocenyl amidinate ligand [Fc?C≡C-{C(Ndipp)2H}] (Fc=ferrocenyl; dipp=diisopropylphenyl) and the subsequent formation of the corresponding samarium amido complex [Sm{Fc?C≡C-[C(Ndipp)2]}2/s
Bora-amidinate as a cooperative ligand in group 2 metal catalysis
Freitag, Benjamin,Fischer, Christian A.,Penafiel, Johanne,Ballmann, Gerd,Elsen, Holger,F?rber, Christian,Piesik, Dirk F.,Harder, Sjoerd
, p. 11192 - 11200 (2017/09/07)
Syntheses and crystal structures of the monomeric bora-amidinate (bam) complexes DIPPNBN-Mg·(THF)3 and DIPPNBN-Ca·(THF)4 are presented; DIPPNBN = HB[N(2,6-iPr2-C6H3)]
Cyclopentadienyl-based Mg complexes in the intramolecular hydroamination of aminoalkenes: Mechanistic evidence for cationic: Versus neutral magnesium derivatives
Gallegos, Carlos,Camacho, Ruth,Valiente, Mercedes,Cuenca, Tomás,Cano, Jesús
, p. 5134 - 5143 (2016/07/07)
Neutral and cationic magnesium complexes stabilized by coordination of a cyclopentadienyl ligand with two different neutral hemilabile donor groups [Mg{η5-C5H3-1,3-(CH2CH2NiPr2)(SiMe2NPh2)}X(thf)] (X = Bz (2); N(SiMe3)2 (3)) and [Mg{η5-C5H3-1,3-(CH2CH2NiPr2)(SiMe2NPh2)}][BPh4] (4) have been prepared and characterized. The 1H-13C HMBC and HSQC spectra of compounds 2 and 3 demonstrate the formation of 1,3-substituted cyclopentadienyl compounds and DOSY and 1H-NMR experiments support the coordination-decoordination in solution of a THF molecule in complex 2. No Schlenk-type ligand redistributions were observed in the chemical behaviour of these magnesium complexes. Compounds 2-4 are active catalysts in the hydroamination of aminoalkenes; stoichiometric reactions and kinetic measurements have been performed to gain an insight into their reaction mechanisms. A key contribution here is the catalytic reactivity of a cationic magnesium compound.