7306-39-0Relevant articles and documents
Cobalt-Catalyzed Aerobic Oxidative Cleavage of Alkyl Aldehydes: Synthesis of Ketones, Esters, Amides, and α-Ketoamides
Li, Tingting,Hammond, Gerald B.,Xu, Bo
supporting information, p. 9737 - 9741 (2021/05/31)
A widely applicable approach was developed to synthesize ketones, esters, amides via the oxidative C?C bond cleavage of readily available alkyl aldehydes. Green and abundant molecular oxygen (O2) was used as the oxidant, and base metals (cobalt and copper) were used as the catalysts. This strategy can be extended to the one-pot synthesis of ketones from primary alcohols and α-ketoamides from aldehydes.
THIAZOLE-2-CARBOXAMIDE DERIVATIVES FOR USE AS HPPAR AGONISTS IN THE TREATMENT OF I.A. DYSLIPIDEMIA
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Page/Page column 9, (2010/02/11)
A compound of formula (I) and pharmaceutically acceptable salts, solvates and hydrolysable esters thereof is claimed for use as a selective dual agonist of PPAR alpha and gamma.
ALLYL- AND BENZYLSTANNANES, NEW REAGENTS IN TERPENIC SYNTHESIS
Andrianome, M.,Haeberle, K.,Delmond, B.
, p. 1079 - 1088 (2007/10/02)
Terpenic allyl- and benzylstannanes are easily prepared from unsaturated terpene hydrocarbons by metallation followed by quenching with trialkyltin chloride.An isomerization of unsaturated terpenes via allyltin compounds is reported, by which (+)-α-pinene has been converted into (+)-β-pinene.A regioselective acylation of allyl- and benzylstannanes are realized by a rhodium-catalyzed coupling with acyl halides.Mono- and sesquiterpenoid ketones which play an important role in the fragrance industry can be obtained.Hydroxylation and oxidation of terpene hydrocarbons via allyl- and benzylstannanes are also reported.