726-94-3Relevant articles and documents
Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer
Primer, David N.,Molander, Gary A.
, p. 9847 - 9850 (2017)
The construction of quaternary centers is a common challenge in the synthesis of complex materials and natural products. Current cross-coupling strategies that can be generalized for setting these centers are sparse and, when known, are typically predicated on the use of reactive organometallic reagents. To address this shortcoming a new, photoredox-Ni dual catalytic strategy for the cross-coupling of tertiary organoboron reagents with aryl halides is reported. In addition to details on the cross-coupling scope and limitations, full screening efforts and mechanistic experiments are communicated.
Alkylation of aromatic compounds with 1-bromoadamantane in the presence of metal complex catalysts
Khusnutdinov,Shchadneva,Khisamova
, p. 1545 - 1550 (2015/12/30)
Synthesis of aryladamantanes was performed by reaction of 1-bromoadamantane with aromatic compounds in the presence of metal complex catalysts containing Mo, Cr, W, Cu, and Co.
Adamantylzinc bromides: Direct preparation and application to cross-coupling reaction
Hwang, Hyung-Seo,Joo, Seong-Ryu,Kim, Seung-Hoi
, p. 2769 - 2772 (2015/11/16)
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