72581-32-9

Basic information

• Product Name: 3-CYCLOHEXENE-1-METHANOL)
• CAS NO: 72581-32-9
• Molecular Formula: C₇H₁₂O
• Molecular Weight: 112.16958
• Mol File: 72581-32-9.mol
• Article Data: 96

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-CYCLOHEXENE-1-METHANOL)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-CYCLOHEXENE-1-METHANOL)(72581-32-9)
• EPA Substance Registry System: 3-CYCLOHEXENE-1-METHANOL)(72581-32-9)

Safety Data

• Hazardous Substances Data: 72581-32-9(Hazardous Substances Data)

Upstream product

• 106-99-0 buta-1,3-diene 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 4771-80-6 1,2,5,6-tetrahydrobenzoic acid 
• 15111-56-5 ethyl-3-cyclohexene-1-carboxylate 
• 3236-44-0 vinyl-2 dihydro-2,3 4H-pyranne 
• 151259-42-6 2-(2-propenyl)hex-5-en-1-ol 
• 145827-23-2 4-<(benzyloxy)methyl>cyclohexene 
• 6493-77-2 methyl cyclohex-3-ene-1-carboxylate 
• 762-72-1 allyl-trimethyl-silane 
• 38447-78-8 4-phenylthiepan-4-ol 
• 1393559-95-9 4-phenylthiepane 1,1-dioxide 
• 1393561-05-1 4-phenyl-2,3,6,7-tetrahydrothiepine 
• 102096-64-0 3-Cyclohexene-1-carboxylic acid (R)-pentalactone ester 
• 1393560-00-3 (S)-(1,1-dioxothiepan-4-yl)methanol 

Downstream Products

• 33324-13-9 (Cyclohex-3-enylmethoxy)-dimethyl-silane 
• 33324-15-1 1-cyclohex-3-enylmethoxy-1,1,3,3-tetramethyl-disiloxane 
• 141258-54-0 acetaldehyde benzyl 1,2,3,6-tetrahydrobenzyl acetal 
• 5708-19-0 (1S)-3-cyclohexenecarboxylic acid 
• 10578-41-3 2-((cyclohex-3-en-1-ylmethoxy)methyl)oxirane 
• 99180-69-5 4-((allyloxy)methyl)cyclohex-1-ene 
• 280-65-9 bicyclo[3.3.1]nonane 
• 6671-66-5 bicyclo[3.3.1]non-2-ene 
• 2568-17-4 bicyclo[3.3.1]nonan-2-one 
• 22482-62-8 3-(cyclohex-3-en-1-yl)propanoic acid 
• 16626-54-3 3-cyclohex-3-enylpropan-1-ol 
• 16626-57-6 4--butylalkohol 
• 27345-73-9 3-Cyclohexenylmethyl-thioacetat 
• 95562-88-2 Vinyl-bis--butan-1.2.4-tricarboxylat 

Relevant articles and documents

Hydrogenation of Esters by Manganese Catalysts

The hydrogenation of esters catalyzed by a manganese complex of phosphine-aminopyridine ligand was developed. Using this protocol, a variety of (hetero)aromatic and aliphatic carboxylates including biomass-derived esters and lactones were hydrogenated to primary alcohols with 63–98% yields. The manganese catalyst was found to be active for the hydrogenation of methyl benzoate, providing benzyl alcohol with turnover numbers (TON) as high as 45,000. Investigation of catalyst intermediates indicated that the amido manganese complex was the active catalyst species for the reaction. (Figure presented.).

Method for synthesizing unsaturated primary alcohol in water phase

The invention discloses a method for synthesizing unsaturated primary alcohol in a water phase. The method comprises the following steps: taking unsaturated aldehyde as a raw material, selecting water as a solvent, and carrying out catalytic hydrogenation reaction on the unsaturated aldehyde in the presence of a water-soluble catalyst to obtain the unsaturated primary alcohol, wherein the catalyst is a metal iridium complex [Cp * Ir (2, 2'-bpyO)(OH)][Na]. Water is used as the solvent, so that the use of an organic solvent is avoided, and the method is more environment-friendly; the reaction is carried out at relatively low temperature and normal pressure, and the reaction conditions are mild; alkali is not needed in the reaction, so that generation of byproducts is avoided; and the conversion rate of the raw materials is high, and the yield of the obtained product is high. The method not only has academic research value, but also has a certain industrialization prospect.and.

Efficient Solvent-Free Hydrosilylation of Aldehydes and Ketones Catalyzed by Fe2(CO)9/C6H4-o-(NCH2PPh2)2BH

An efficient solvent-free catalyst system for hydrosilylation of aldehydes and ketones was developed based on iron pre-catalyst Fe2(CO)9/C6H4-o-(NCH2PPh2)2BH. The reactions were tolerant of many functional groups and the corresponding alcohols were isolated in good to excellent yields following basic hydrolysis of the reaction products. The reaction is likely catalyzed by an in situ generated pincer ligated iron hydride complex. Graphic Abstract: [Figure not available: see fulltext.]