6876-65-9

Basic information

• Product Name: Benzeneacetamide, N-(4-methylphenyl)-
• CAS NO: 6876-65-9
• Molecular Formula: C15H15NO
• Molecular Weight: 225.29
• Mol File: 6876-65-9.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: Benzeneacetamide, N-(4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetamide, N-(4-methylphenyl)-(6876-65-9)
• EPA Substance Registry System: Benzeneacetamide, N-(4-methylphenyl)-(6876-65-9)

Safety Data

• Hazardous Substances Data: 6876-65-9(Hazardous Substances Data)

Upstream product

• 110915-73-6 anhydride N-acetyl phenyl-acetohydroxamique-acetique 
• 5720-05-8 4-methylphenylboronic acid 
• 31614-66-1 tributyl(p-tolyl)stannane 
• 103-83-3 N,N'-dimethylbenzylamine 
• 25083-02-7 1-(2-phenylacetyl)pyrrolidin-2-one 
• 106-49-0 p-toluidine 
• 260783-80-0 N,N,N--trimethyl--1--phenylmethanaminium trifluoromethanesulfonate 
• 99-99-0 1-methyl-4-nitrobenzene 
• 13939-06-5 molybdenum hexacarbonyl 
• 3085-54-9 N-(4-methylphenyl)formamide 
• 108-88-3 toluene 
• 106-43-4 para-chlorotoluene 
• 103-81-1 Benzeneacetamide 
• 201230-82-2 carbon monoxide 

Downstream Products

• 103-81-1 Benzeneacetamide 
• 19711-87-6 2-oxo-2-diphenyl-N-(p-tolyl)acetamide 
• 1253778-98-1 2-phenyl-N-(4-((N-(phenylsulfonyl)phenylsulfonamido)methyl)phenyl)acetamide 
• 73108-78-8 6-methyl-3-phenylquinolin-2(1H)-one 
• 934495-95-1 2-phenyl-N-p-tolyl-acetimidoyl chloride 
• 681455-21-0 N-[1-(benzotriazol-1-yl)-2-phenylethylidene]-4-methylaniline 
• 90362-96-2 6-methyl-2-(phenylmethyl)-4(3H)-quinazolinone 

Relevant articles and documents

Metal-free transamidation of benzoylpyrrolidin-2-one and amines under aqueous conditions

N-Acyl lactam amides, such as benzoylpyrrolidin-2-one, benzoylpiperidin-2-one, and benzoylazepan-2-one reacted with amines in the presence of DTBP and TBAI to afford the transamidated products in good yields. The reactions were conducted under aqueous conditions and good functional group tolerance was achieved. Both aliphatic and aromatic primary amines displayed good activity under metal-free conditions. A radical reaction pathway is proposed.

Nickel (II)-Catalyzed efficient aminocarbonylation of unreactive alkanes with formanilides—Exploiting the deformylation behavior of imides

Challenging functionalization of C(sp3)-H has recently attracted much attention of organic chemists. In this paper, we developed a Ni(acac)2-catalyzed activation of unreactive alkanes with formanilides in the presence of carbon monoxide to furnish moderate to excellent yields of amides. This is the first example of aminocarbonylation of inert alkanes using nickel-based catalyst, and formanilides is disclosed to be an interesting amine source owing to the peculiar deformylation nature of imide intermediates.

Organocatalytic Asymmetric Annulation between Hydroxymaleimides and Nitrosoarenes: Stereoselective Preparation of Chiral Quaternary N-Hydroxyindolines

An unusual and highly effective asymmetric annulation of nitrosoarenes with hydroxymaleimides catalyzed by a chiral bifunctional amine squaramide catalyst has been disclosed. A wide range of highly fused chiral N-hydroxyindolines with two consecutive quaternary stereocenters and multifunctional groups were directly and effectively prepared in excellent yields (up to >99%) with complete regioselective cyclization and excellent stereoselectivities (up to >99:1 dr and >99% ee). The efficiency and potentials of the new reaction and the target chiral entities were well demonstrated by delicate transformations into a series of new chiral indolines.