66778-06-1Relevant articles and documents
Chemistry of phosphorus ylides: Part 44 reaction of 1-trimethylsilyl-1H-imidazole with phosphorus reagents. A convenient synthesis of phosphorus silyl imidazoles
El-Hussieny, Marwa,Abd-El-Maksoud, Mansoura Ali,Maigali, Soher Said,Soliman, Fouad Mohamed
, p. 265 - 268 (2016/07/06)
The reaction of 1-trimethylsilyl-1H-imidazole with nucleophilic active phosphacumulenes afforded imidazole silyl phosphoranylidenes or imidazole phosphoranylidenes according to the reaction conditions. The reaction of hexaphenylcarbodiphosphorane with 1-trimethylsilyl-1H-imidazole resulted in the formation of silyl phosphoranylidene phosphoranyl imidazole, silyl phosphoranylidene imidazole and triphenylphosphane. Moreover, Lawesson and Japanese reagents afforded imidazole phosphinothioic thioanhydrides.