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656233-53-3

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  • (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP

    Cas No: 656233-53-3

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  • Strem Chemicals, Inc.
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656233-53-3 Usage

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Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids. Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids. Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.

Check Digit Verification of cas no

The CAS Registry Mumber 656233-53-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,5,6,2,3 and 3 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 656233-53:
(8*6)+(7*5)+(6*6)+(5*2)+(4*3)+(3*3)+(2*5)+(1*3)=163
163 % 10 = 3
So 656233-53-3 is a valid CAS Registry Number.

656233-53-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite,(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1′,7′-fg][1,3,2]dioxaphosphocin-5-phenoxy

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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More Details:656233-53-3 SDS

656233-53-3Downstream Products

656233-53-3Relevant articles and documents

Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands

Shi, Wen-Jian,Wang, Li-Xin,Fu, Yu,Zhu, Shou-Fei,Zhou, Qi-Lin

, p. 3867 - 3872 (2007/10/03)

The copper complexes of chiral spiro phosphoramidite and phosphite ligands were found to be effective catalysts in the asymmetric allylic alkylations of cinnamyl halides with dialkylzincs. The allylic alkylation products were obtained in high regioselecti

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