6372-41-4

Basic information

• Product Name: BUTYLDIPHENYLPHOSPHINE
• Synonyms: Butyl(diphenyl)phosphine;Phosphine, butyldiphenyl-;Diphenylbutylphosphine;Einecs 228-903-7
• CAS NO: 6372-41-4
• Molecular Formula: C₁₆H₁₉P
• Molecular Weight: 242.295821
• EINECS: 228-903-7
• Mol File: 6372-41-4.mol
• Article Data: 29

Chemical Properties

• Boiling Point: 361.3°C at 760 mmHg
• Flash Point: 161.1°C
• Appearance: /
• Vapor Pressure: 4.34E-05mmHg at 25°C
• CAS DataBase Reference: BUTYLDIPHENYLPHOSPHINE(CAS DataBase Reference)
• NIST Chemistry Reference: BUTYLDIPHENYLPHOSPHINE(6372-41-4)
• EPA Substance Registry System: BUTYLDIPHENYLPHOSPHINE(6372-41-4)

Safety Data

• Hazardous Substances Data: 6372-41-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H19P/c1-2-3-14-17(15-10-6-4-7-11-15)16-12-8-5-9-13-16/h4-13H,2-3,14H2,1H3

Upstream product

• 109-69-3 n-Butyl chloride 
• 591-51-5 phenyllithium 
• 109-72-8 n-butyllithium 
• 1079-66-9 chloro-diphenylphosphine 
• 1779-51-7 n-butyl(triphenyl)phosphonium bromide 
• 109-65-9 1-bromo-butane 
• 829-85-6 diphenylphosphane 
• 65567-06-8 lithium diphenylphosphide 
• 603-35-0 triphenylphosphine 
• 4233-13-0 butyldiphenylphosphine oxide 
• 17154-34-6 (trimethylsilyl)diphenylphosphine 
• 4376-01-6 sodium diphenylphosphide 
• 18437-78-0 P(p-C₆H₄F)3 
• 1159415-87-8 2-(diphenylphosphanyl)-N-(2'-diphenylphosphanyl-1'-naphthyl)-N'-methyl-1H-benzimidazolium trifluoromethanesulfonate 

Downstream Products

• 4233-13-0 butyldiphenylphosphine oxide 
• 10251-55-5 butyl(phenyl)phosphine 
• 433-97-6 2-trifluoromethylbenzoic acid 
• 101897-21-6 bromo(n-butyldiphenylphosphine)gold(I) 
• 121567-29-1 Au(P(C₆H₅)2(CH₂)3CH₃)3⁽¹⁺⁾*Br^(1-)={Au(P(C₆H₅)2(CH₂)3CH₃)3}Br 
• 121567-28-0 bromobis(n-butyldiphenylphosphine)gold(I) 
• 24545-71-9 trans-(CO)4Cr{P(C₄H₉)Ph₂}2 
• 128594-26-3 bromo(tetracarbonyl)(butyldiphenylphosphane)manganese(I) 
• 112312-65-9 {RhH(CO)(P(C₆H₅)2(C₄H₉))3} 
• 170656-77-6 [Os3(μ-H)2(CO)9(μ3-CPBu(n)Ph2)] 
• 56629-94-8 trans-[Co(dimethylglyoximato^(1-))2(n-butyldiphenylphosphine)Cl] 

Relevant articles and documents

Catalytic Cleavage of Unactivated C(aryl)-P Bonds by Chromium

We describe here the coupling to transform aryl phosphine derivatives by the cleavage of unactivated C(aryl)-P bonds with chromium catalysis, allowing us to achieve the reaction with alkyl bromides and arylmagnesium reagents under mild conditions. Mechani

Palladium-catalyzed C(sp3)–P(III) bond formation reaction with acylphosphines as phosphorus source

Palladium-catalyzed C(sp3)–P(III) bond formation reaction for alkyl substituted phosphines preparation was developed. In this reaction, various alkyl bromides and limited alkyl chlorides reacted with acylphosphine under relative mild and easily accessible condition, and differential phosphines were afforded in good yields. This reaction made up the application of palladium catalysis in C(sp3)–P(III) bond formation, and indicated a practical application of acylphosphine as a phosphination reagent.

Selective C-P(O) Bond Cleavage of Organophosphine Oxides by Sodium

Sodium exhibits better efficacy and selectivity than Li and K for converting Ph3P(O) to Ph2P(OM). The destiny of PhNa co-generated is disclosed. A series of alkyl halides R4X and aryl halides ArX all react with Ph2P(ONa) to produce the corresponding phosphine oxides in good to excellent yields.