63536-44-7

Basic information

• Product Name: 2(1H)-Quinoxalinone, 1-(phenylmethyl)-
• CAS NO: 63536-44-7
• Molecular Formula: C15H12N2O
• Molecular Weight: 236.273
• Mol File: 63536-44-7.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: 2(1H)-Quinoxalinone, 1-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2(1H)-Quinoxalinone, 1-(phenylmethyl)-(63536-44-7)
• EPA Substance Registry System: 2(1H)-Quinoxalinone, 1-(phenylmethyl)-(63536-44-7)

Safety Data

• Hazardous Substances Data: 63536-44-7(Hazardous Substances Data)

Upstream product

• 1196-57-2 quinoxalin-2⁽¹⁾-one 
• 1196-57-2 2-hydroxyquinoxaline 
• 100-39-0 benzyl bromide 
• 14003-34-0 3-methyl-2-oxo-1,2-dihydroquinoxaline 
• 100-44-7 benzyl chloride 
• 59564-59-9 1,2,3,4-tetrahydroquinoxalin-2-one 
• 5428-05-7 n-(2-nitrophenyl)glycine ethyl ester 
• 1493-27-2 ortho-nitrofluorobenzene 
• 100-46-9 benzylamine 
• 95-54-5 1,2-diamino-benzene 
• 1239573-83-1 N-benzyl-2-chloro-N-(2-bromophenyl)acetamide 
• 1239573-73-9 N-benzyl-2-chloro-N-(2-iodophenyl)-acetamide 
• 2564-06-9 N-benzyl-2-chloroacetamide 
• 116547-92-3 N-(2-iodophenyl)methanesulfonamide 

Downstream Products

• 84546-74-7 3-methyl-1-benzylquinoxaline-2(1H)-one 

Relevant articles and documents

Electro-reductive C-H cyanoalkylation of quinoxalin-2(1H)-ones

Herein, we report a practical electro-reductive protocol for the direct C–H cyanoalkylation of quinoxalin-2(1H)-ones via iminyl radical-mediated ring opening. These mild reactions proceed under metal-, reductant-, and reagent-free conditions to provide synthetically useful cyanoalkylated quinoxalin-2(1H)-ones.

Method for catalytically preparing 3-sulfur substituted quinoxalinone derivative

The invention relates to a method for catalytically preparing a 3-sulfur substituted quinoxalinone derivative. The method comprises the following steps of: firstly preparing a 3-(thiophenyl) quinoxaline-2 (1H)-ketone derivative, then adding the 3-(thiophenyl) quinoxaline-2 (1H)-ketone derivative, disulfide, an oxidizing agent and a catalyst into a reaction container, adding a solvent, reacting under the light irradiation of a blue lamp, and after the reaction is completed, filtering, extracting, concentrating, separating and purifying to obtain the 3-sulfur substituted quinoxalinone derivative. According to the invention, the problem that a traditional catalyst needs high-temperature reaction is solved, disulfide is used as a raw material, the problem that foul thiophenol and thiol substances are used as raw materials traditionally is solved, and a green and efficient synthesis method is used to promote industrialization of a reaction system; and meanwhile, quinoxalinone compounds with different substituent groups are also efficiently expanded.

Light-driven selective aerobic oxidation of (iso)quinoliniums and related heterocycles

Selective C1-H/C4-H carbonylation of N-methylene iminium salts, catalyzed by visible-light photoredox and oxygen in the air, has been reported. A ruthenium complex acts as a chemical switch to conduct two different reaction pathways and to afford two diff