617-00-5

Basic information

• Product Name: N-(2-Methylphenyl)-2-methylbenzenamine
• Synonyms: 2,2'-Ditolylamine;2,2'-Iminobis(methylbenzene);2-Methyl-N-(2-methylphenyl)benzenamine;4-12-238;Bis(o-tolyl)amine;N-(2-Methylphenyl)-2-methylbenzenamine
• CAS NO: 617-00-5
• Molecular Formula: C₁₄H₁₅N
• Molecular Weight: 197.2756
• Mol File: 617-00-5.mol
• Article Data: 50

Chemical Properties

• Melting Point: 52.5°C
• Boiling Point: 324.39°C (rough estimate)
• Flash Point: 147.1°C
• Appearance: /
• Density: 1.0514 (rough estimate)
• Vapor Pressure: 0.000555mmHg at 25°C
• Refractive Index: 1.6095 (estimate)
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• PKA: 0.53±0.40(Predicted)
• CAS DataBase Reference: N-(2-Methylphenyl)-2-methylbenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-Methylphenyl)-2-methylbenzenamine(617-00-5)
• EPA Substance Registry System: N-(2-Methylphenyl)-2-methylbenzenamine(617-00-5)

Safety Data

• Hazardous Substances Data: 617-00-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H15N/c1-11-7-3-5-9-13(11)15-14-10-6-4-8-12(14)2/h3-10,15H,1-2H3

Upstream product

• 95-49-8 2-methylchlorobenzene 
• 95-46-5 2-methylphenyl bromide 
• 120-66-1 N-(2-methylphenyl)acetamide 
• 95-48-7 ortho-cresol 
• 636-21-5 o-toluidine hydrochloride 
• 95-53-4 o-toluidine 
• 142-04-1 aniline hydrochloride 
• 615-37-2 ortho-methylphenyl iodide 
• 19020-41-8 N-acetyl-2,2'-dimethyldiphenylamine 
• 108-41-8 1-chloro-3-methylbenzene 
• 7003-32-9 2-METHYLCYCLOHEXYLAMINE 
• 583-60-8 2-Methylcyclohexanone 
• 16419-60-6 2-Methylphenylboronic acid 
• 2093-46-1 2-methylphenyl diazonium tetrafluoroborate 

Downstream Products

• 1373131-53-3 N-(4-bromophenyl)-2-methyl-N-(o-tolyl)aniline 
• 1373131-54-4 2-methyl-N-(2-methylphenyl)-N-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]benzenamine 
• 1613149-61-3 N-(4-(5-bromopyrazin-2-yl)phenyl)-2-methyl-N-(o-tolyl)aniline 
• 1613149-52-2 2-methyl-N-(4-(5-(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)pyrazin-2-yl)phenyl)-N-(o-tolyl)aniline 
• 49785-66-2 2-methyl-N-phenyl-N-(o-tolyl)aniline 
• 1629189-68-9 C₂₁H₂₁N 
• 49785-51-5 2-(di-o-tolylamino)benzoic acid 
• 49785-50-4 N_.N-Di-o-tolylanthranilsaeuremethylester 

Relevant articles and documents

Highly efficient chrysene emitters based on optimized side groups for deep blue emission

Diphenylamine substituted with methyl groups was used as a side group to realize high efficiency chrysene deep blue emitters. Three chrysene derivatives substituted with side groups were successfully synthesized: tetra-o-tolylchrysene-6,12-diamine (o-DPAC

Method for synthesizing organic aromatic nitrogen-containing compound by taking nitrogen as nitrogen source

The invention provides a method for synthesizing an organic aromatic nitrogen-containing compound by taking nitrogen as a nitrogen source, and belongs to the field of organic synthesis. The invention provides a method for synthesizing an organic aromatic nitrogen-containing compound by taking nitrogen as a nitrogen source, which is characterized by comprising the following steps of: 1, reducing nitrogen by lithium powder to form lithium nitride; and 2, reacting the lithium nitride with a halogenated aromatic compound under the action of a transition metal catalyst, a ligand, alkali and a phase transfer catalyst to obtain an organic aromatic nitrogen-containing compound; wherein the two steps of reactions are completed in one pot. The method realizes the conversion of cheap nitrogen to the high-added-value aromatic nitrogen-containing compound, and also has the advantages of mild reaction conditions, good compatibility of substrate functional groups, high yield and the like.

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This work reports the selective one-pot synthesis of symmetrical and asymmetrical amines from guanidines as ammonia surrogate. The use of guanidine as ammonia source will eliminate the need of handling liquid ammonia. The reaction was performed using Cu/Cu2O nanocatalyst under ligand-free condition. The synthesized catalyst was characterized by a various technique like XRD, FEG-SEM, HRTEM and XPS. The different diphenylamines are produced in good to very good yields. Recyclability study of catalyst shows that up to five cycles there is no significant loss in its activity.

1,9,10-SUBSTITUTED PHENATHIAZINE DERIVATIVES WITH STRAINED RADICAL CATIONS AND USE THEREOF

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