613-87-6

Basic information

• Product Name: (S)-(-)-1-PHENYL-1-PROPANOL
• Synonyms: (S)-(-)-ALPHA-ETHYLBENZYL ALCOHOL;(S)-ALPHA-ETHYLBENZYL ALCOHOL;(S)-(-)-1-PHENYL-1-PROPANOL;(S)-1-PHENYLPROPAN-1-OL;(S)-1-PHENYL-PROPANOL;(S)-(-)-1-PHENYL-1-PROPANOL, 99% (99% EE /GLC);S-(-)-1-PHENYL-1-PROPANOL 99+%;(S)-(-)-1-Phenyl-1-propanol, 98% ee, 95%
• CAS NO: 613-87-6
• Molecular Formula: C₉H₁₂O
• Molecular Weight: 136.19
• Product Categories: Alcohols, Hydroxy Esters and Derivatives;Chiral Compounds;Alcohols and Epoxides;CHIRAL CHEMICALS
• Mol File: 613-87-6.mol
• Article Data: 644

Chemical Properties

• Boiling Point: 94-95 °C10 mm Hg(lit.)
• Flash Point: 90 °C
• Appearance: /
• Density: 0.992 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.520(lit.)
• Storage Temp.: Store below +30°C.
• Solubility: 10.33g/l
• PKA: 14.43±0.20(Predicted)
• Water Solubility: Slightly soluble in water.
• BRN: 2041556
• CAS DataBase Reference: (S)-(-)-1-PHENYL-1-PROPANOL(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-1-PHENYL-1-PROPANOL(613-87-6)
• EPA Substance Registry System: (S)-(-)-1-PHENYL-1-PROPANOL(613-87-6)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• Safety Statements: 23-24/25
• RIDADR: UN 2810 6.1/PG 3
• WGK Germany: 3
• RTECS: DO5470000
• Hazardous Substances Data: 613-87-6(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless liquid

Upstream product

• 766-90-5 cis-1-phenyl-1-propylene 
• 82009-50-5 <2S-(2α(R*),3aα,4α,7α,7aα)>-2,3,3a,4,5,6,7,7a-Octahydro-7,8,8-trimethyl-2-(1-phenylpropoxy)-4,7-methanobenzofuran 
• 2114-29-6 (S)-1-phenylpropyl acetate 
• 103-65-1 phenylpropane 
• 93-54-9 1-Phenyl-1-propanol 
• 97-72-3 2-Methylpropionic anhydride 
• 108-22-5 Isopropenyl acetate 
• 93-55-0 1-phenyl-propan-1-one 
• 75-52-5 nitromethane 
• 557-20-0 diethylzinc 
• 100-52-7 benzaldehyde 
• 108-24-7 acetic anhydride 
• 97-93-8 triethylaluminum 
• 108-05-4 vinyl acetate 

Downstream Products

• 2114-29-6 (S)-1-phenylpropyl acetate 
• 1016274-95-5 C₁₄H₁₆N₂O₂ 
• 118-12-7 1,3,3-Trimethyl-2-methyleneindoline 
• 190506-77-5 (R)-1-phenyl-propyl hydroperoxide 
• 1678-92-8 propylcyclohexane 
• 110529-28-7 (S)-1-cyclohexylpropan-1-ol 
• 1622202-15-6 (1S,2S,3Z)-1-hydroxy-2,3-dimethyl-1,4-diphenylhex-3-ene 
• 1622202-01-0 (2E,4S)-3-methyl-4-phenyl-4-(4',4',5',5'-tetramethyl-1’,3’,2’-dioxaborolanyl)hex-2-ene 
• 1609649-62-8 (S)-N-(1-(1-phenylpropyl)-1H-pyrazol-4-yl)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-indazole-3-carboxamide 
• 1228952-51-9 C₁₉H₁₈FNO₂ 

Relevant articles and documents

Synthesis of a new class of chiral aminoalcohols and their application in the enantioselective addition of diethylzinc to aldehydes

Five new aminoalcohols containing a 2,2'-bridged binaphthyl entity were synthesised and applied as auxiliaries in the enantioselective addition of Et2Zn to ten aldehydes. While reactivities were generally high and low concentrations of aminoalc

Chiral Yolk-Shell MOF as an Efficient Nanoreactor for Asymmetric Catalysis in Organic-Aqueous Two-Phase System

It remains a great challenge to introduce large and efficient homogeneous asymmetric catalysts into MOFs and other microporous materials as well as retain their degrees of freedom. Herein, a new heterogeneous strategy of homogeneous chiral catalysts is proposed, that is, to construct a yolk-shell MOFs-confined, large-size, and highly efficient homogeneous chiral catalyst, which can be used as a nanoreactor for asymmetric catalytic reactions.

Visible-Light-Driven Catalytic Deracemization of Secondary Alcohols

Deracemization of racemic chiral compounds is an attractive approach in asymmetric synthesis, but its development has been hindered by energetic and kinetic challenges. Here we describe a catalytic deracemization method for secondary benzylic alcohols which are important synthetic intermediates and end products for many industries. Driven by visible light only, this method is based on sequential photochemical dehydrogenation followed by enantioselective thermal hydrogenation. The combination of a heterogeneous dehydrogenation photocatalyst and a chiral molecular hydrogenation catalyst is essential to ensure two distinct pathways for the forward and reverse reactions. These reactions convert a large number of racemic aryl alkyl alcohols into their enantiomerically enriched forms in good yields and enantioselectivities.