5958-61-2

Basic information

• Product Name: 1-phenyl-3-methyl-3-phospholene 1-sulfide
• Synonyms: 1-phenyl-3-methyl-3-phospholene 1-sulfide
• CAS NO: 5958-61-2
• Molecular Weight: 208.264
• Mol File: 5958-61-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-phenyl-3-methyl-3-phospholene 1-sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-3-methyl-3-phospholene 1-sulfide(5958-61-2)
• EPA Substance Registry System: 1-phenyl-3-methyl-3-phospholene 1-sulfide(5958-61-2)

Safety Data

• Hazardous Substances Data: 5958-61-2(Hazardous Substances Data)

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 78-79-5 isoprene 
• 7564-51-4 2,5-dihydro-3-methyl-1-phenyl-1H-phosphole 1-oxide 

Relevant articles and documents

The deoxygenation of phosphine oxides under green chemical conditions

The deoxygenation of a few diaryl-phenylphosphine oxides, dimethyl-phenylphosphine oxide, and 3-methyl-1-phenyl-3-phospholene 1-oxide was studied by phenylsilane, tetramethyldisiloxane (TMDS), and polymethylhydrosiloxane (PMHS) under conventional or microwave (MW) heating, in toluene or in the absence of any solvent at different temperatures. It was found that the deoxygenation with TMDS or PMHS under MW and solvent-free conditions may be the method of choice and provides a green chemical approach.

Synthesis of functionalized P-heterocycles including phosphine-borane complexes

Preparation of phosphinic chlorides, amides, and sulfide derivatives, as well as phosphine-borane complexes of P-heterocycles is described.