5707-06-2

Basic information

• Product Name: O,O-diethyl Se-phenyl phosphoroselenoate
• Synonyms: O,O-diethyl Se-phenyl phosphoroselenoate
• CAS NO: 5707-06-2
• Molecular Weight: 293.161
• Mol File: 5707-06-2.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: O,O-diethyl Se-phenyl phosphoroselenoate(CAS DataBase Reference)
• NIST Chemistry Reference: O,O-diethyl Se-phenyl phosphoroselenoate(5707-06-2)
• EPA Substance Registry System: O,O-diethyl Se-phenyl phosphoroselenoate(5707-06-2)

Safety Data

• Hazardous Substances Data: 5707-06-2(Hazardous Substances Data)

Upstream product

• 52251-58-8 lithium phenylselenide 
• 814-49-3 diethyl chlorophosphate 
• 68819-94-3 p-tolyl benzeneselenosulfonate 
• 122-52-1 triethyl phosphite 
• 1666-13-3 diphenyl diselenide 
• 2303-76-6 sodium diethyl phosphite 
• 762-04-9 phosphonic acid diethyl ester 
• 34837-55-3 Phenylselenyl bromide 
• 923-99-9 tri-n-propyl phosphite 
• 5707-04-0 Phenylselenyl chloride 
• 2179-79-5 phenyl selenocyanate 
• 645-96-5 Benzeneselenol 

Downstream Products

• 62935-06-2 O,O-Diaethyl-Se-phenylphosphordiselenoat 
• 1068-07-1 diethyl octylphosphonate 
• 19821-02-4 O,O-diethyl-Se-phenyl phosphoroselenothioate 
• 63909-49-9 O,O-diethyl (cyclohexylmethyl)phosphonate 
• 34837-55-3 Phenylselenyl bromide 
• 1666-13-3 diphenyl diselenide 
• 762-04-9 phosphonic acid diethyl ester 
• 934817-79-5 diethyl (2,3-O-isopropylidene-5-O-tert-butyldiphenylsilanyl-D-ribofuranos-1yl)difluoromethylenephosphonate 

Relevant articles and documents

Sulfonyl-Promoted Michaelis-Arbuzov-Type Reaction: An Approach to S/Se-P Bonds

By facilitating the chemical conversion of thiols to thiosulfonates, phosphoramidite/phosphite bearing sp3-hybridized carbon serves as an ideal coupling material to forge new connections at room temperature. In this work, a functional group-induced, additive-free, novel, S-P bond-forming approach is presented. This protocol exhibits good functional group tolerance with wide applications that include phosphorylation of cysteine derivatives, development of a one-pot approach to mixed unsymmetrical thiophosphonates, and extension of the concept to different Se-P bonds. Meticulously, our reaction also generated a S-P bond against cyclic 1,2-dithiane-1-dioxide in a byproduct-free manner. These Michaelis-Arbuzov-type reactions are easy to conduct, work efficiently in a reduced reaction time, and are applicable to gram-scale preparation as well.

Electrochemical selenation of phosphonates and phosphine oxides

An environmentally friendly electrocatalytic strategy for the synthesis of organoselenophospho-rus between phosphonates /phosphine oxides and selenols/diselenides is reported. The reaction was performed with metal-, base- and oxidant-free at room temperat

Highly atom-economical, catalyst-free, and solvent-free phosphorylation of chalcogenides

Silica gel promoted, catalyst-free and solvent-free S-P, Se-P and Te-P bond formations are described. A variety of disulfides coupled with diarylphosphine oxides provide the corresponding phosphinothioates in excellent yields. For the first time, diselenides and ditellurides reacted with dialkyl phosphites under catalyst-free conditions to provide the corresponding phosphoroselenoates and phosphorotelluroates, respectively, in good to excellent yields.