57057-23-5Relevant articles and documents
Acetonitrile-dependent oxyphosphorylation: A mild one-pot synthesis of β-ketophosphonates from alkenyl acids or alkenes
Chen, Xi,Chen, Xiaolan,Li, Xu,Qu, Chen,Qu, Lingbo,Bi, Wenzhu,Sun, Kai,Zhao, Yufen
, p. 2439 - 2446 (2017/04/03)
An efficient one-pot synthesis of β-ketophosphonates has been developed, via the reaction of α,β-alkenyl carboxylic acids or alkenes with H-phosphonates and air oxygen, catalyzed by CuSO4·5H2O in CH3CN. CH3CN plays a decisive role, probably by forming an active oxygen complex [(MeCN)nCuII-O-O·].