5355-17-9Relevant articles and documents
Stewart
, p. 2662 (1962)
A method of manufacturing a lignocellulose compd. (by machine translation)
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Paragraph 0058-0062; 0066-0070, (2018/02/24)
PROBLEM TO BE SOLVED: To provide a production method capable of obtaining a high-purity benzyl ether compound at excellent yield by a simple method. SOLUTION: This invention relates to a method for producing a benzyl ether compound represented by general formula (In the formula, R1-R3each represents a hydrogen atom, a 1-3C alkyl group, or a 1-3C alkoxy group, and R4represents a 1-3C alkyl group) which is obtained by reacting a benzyl alcohol compound having a phenol group with an aliphatic alcohol compound in the presence of an inorganic acid and a nitro compound. COPYRIGHT: (C)2013,JPO&INPIT
Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst
Wang, Feng,Yang, Guanyu,Zhang, Wei,Wu, Wenhai,Xu, Jie
, p. 633 - 638 (2007/10/03)
A high-yield synthesis of p-hydroxybenzaldehyde from p-cresol and molecular oxygen was achieved over a CuMn-oxide supported carbon catalyst. The reaction parameters such as pressure, stirring speed, reaction temperature, solvent, and the amount of sodium hydroxide in the reaction media were optimized. As a result, a high conversion of p-cresol (99%) and a high selectivity to p-hydroxybenzaldehyde (96%) were realized at the same time. Catalyst separation and recycling tests clearly showed that the reaction proceeded on the heterogeneous catalyst but not on dissolved species.