52184-19-7Relevant articles and documents
Preparation method of ultraviolet absorber UV-328
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Paragraph 0031;0035, (2019/10/01)
A preparation method of an ultraviolet absorber UV-328 is provided. The method includes o-nitrochlorobenzene ammoniation, diazotization, coupling, a first reduction step, a second reduction reaction and after-treatment to prepare a 2-(2'-hydroxyl-3',5'-di-tert-amyl phenyl) benzotriazole product. Ammonia water having a concentration of 10-25% is adopted for o-nitrochlorobenzene ammoniation, then diazotization is performed with nitrite to generate a diazonium salt, the diazotization does not need a strong acidic medium, and the ammonia water which is a byproduct of products of the company is comprehensively utilized, thus achieving low emission of three wastes and a low cost. Reduction for ring closing of an intermediate azo product adopts a two-step reduction process, avoiding a situation that a strong reductant directly reduces azo double bonds into amine, reducing impurity generation, increasing product purity and increasing the product yield.