51937-00-9 Usage
Description
Z,E-9,12-TETRADECADIEN-1-OL, also known as (Z,E)-9,12-tetradecadien-1-ol, is a naturally occurring organic compound that belongs to the class of secondary alcohols. It is characterized by the presence of two carbon-carbon double bonds in its structure, with one being in the Z configuration and the other in the E configuration. Z,E-9,12-TETRADECADIEN-1-OL is known for its distinct chemical properties and potential applications in various industries.
Uses
Used in Insect Control Applications:
Z,E-9,12-TETRADECADIEN-1-OL is used as an insect attractant, particularly for the management of pest populations in agricultural and horticultural settings. It serves as a potent lure for specific insects, enabling effective control and reduction of their numbers.
Used in Pheromone-based Pest Management:
In the field of pest control, Z,E-9,12-TETRADECADIEN-1-OL is utilized as a key component in the sex pheromone of Plodia interpunctella, a common pest known as the Indianmeal moth. By mimicking the natural pheromone released by female moths to attract males, this compound is used to disrupt mating patterns and reduce the overall population of the pest, thus providing an eco-friendly and targeted approach to pest management.
Used in Chemical Ecosystems:
Z,E-9,12-TETRADECADIEN-1-OL also plays a role in chemical ecosystems, where it can be employed as a signaling molecule to influence the behavior of various insect species. This application can be particularly useful in research and monitoring efforts aimed at understanding and managing insect populations in different environments.
Check Digit Verification of cas no
The CAS Registry Mumber 51937-00-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,1,9,3 and 7 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 51937-00:
(7*5)+(6*1)+(5*9)+(4*3)+(3*7)+(2*0)+(1*0)=119
119 % 10 = 9
So 51937-00-9 is a valid CAS Registry Number.
InChI:InChI=1/C14H26O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-3,5-6,15H,4,7-14H2,1H3/b3-2-,6-5+
51937-00-9Relevant articles and documents
SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS
-
Paragraph 0110, (2018/09/12)
Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.
Concise syntheses of insect pheromones using Z-Selective cross metathesis
Herbert, Myles B.,Marx, Vanessa M.,Pederson, Richard L.,Grubbs, Robert H.
supporting information, p. 310 - 314 (2013/02/23)
Very short synthetic routes to nine cisolefin-containing pheromones containing a variety of functionality, including an unconjugated (E,Z) diene, are reported (see scheme). These lepidopteran pheromones are used extensively for pest control, and were easily prepared using ruthenium-based Z-selective cross metathesis, highlighting the advantages of this method over less efficient ways to form Z olefins.
Stereodirectional synthesis of the main component of pheromone (9Z,12E)-tetradeca-9,12-dienyl acetate by cross-coupling
Matveeva,Erin,Leshcheva,Kurts
, p. 765 - 770 (2007/10/03)
By cross-coupling of alkynyl cuprate with crotyl halides was synthesized (9Z,12E)-tetradeca-9-12-dienyl acetate, the main component of pheromones of several insect species Lepidoptera. The assignment of the chemical shifts of diene system was performed by 1H and 13NMR spectroscopy.
