506417-41-0 Usage
Description
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is a chemical compound with the formula [RuCl2(PPh2CH2CH3)4], where PPh2 represents diphenylphosphino groups and CH2CH3 represents ethyl groups. It is a type of organometallic complex that contains ruthenium as the central metal atom. DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is known for its catalytic properties and is widely used in various chemical reactions.
Uses
1. Used in Chemical Synthesis:
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is used as a catalyst for the synthesis of long chain linear fatty acid esters. Its ability to facilitate the formation of these esters makes it a valuable component in the production of various chemicals and materials.
2. Used in Hydrogenation Reactions:
In the field of organic chemistry, DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is used as a catalyst in the preparation of ruthenium borohydride complexes. These complexes are essential for carrying out hydrogenation reactions, which are crucial in the production of various pharmaceuticals, agrochemicals, and fine chemicals.
3. Used in Dehydrogenation of Ammonia Boranes:
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is also employed as a catalyst in the dehydrogenation of ammonia boranes. This process is significant in the field of hydrogen storage and energy production, as it helps in the conversion of ammonia boranes into useful hydrogen sources.
4. Used in Chemoselective Reduction:
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is used as a catalyst for the chemoselective reduction of carboxylic esters. This selective reduction is essential in the synthesis of specific organic compounds, as it allows for the preferential reduction of certain functional groups without affecting others.
5. Used in Synthesis of Ruthenium Beta-Aminophosphine Hydrazido/Chloro Complexes:
DICHLOROBIS(2-(DIPHENYLPHOSPHINO)ETHYLA& is utilized in the synthesis of ruthenium beta-aminophosphine hydrido/chloro complexes. These complexes exhibit catalytic activities in various chemical reactions, making them valuable in the development of new synthetic methods and processes.
Reaction
Efficient catalyst for the dihydrogen reduction of carboxylic esters and amides to alcohols.
Check Digit Verification of cas no
The CAS Registry Mumber 506417-41-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,0,6,4,1 and 7 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 506417-41:
(8*5)+(7*0)+(6*6)+(5*4)+(4*1)+(3*7)+(2*4)+(1*1)=130
130 % 10 = 0
So 506417-41-0 is a valid CAS Registry Number.
InChI:InChI=1/2C14H16NP.2ClH.Ru/c2*15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14;;;/h2*1-10H,11-12,15H2;2*1H;/q;;;;+2/p-2
506417-41-0Relevant articles and documents
CATALYTIC CONVERSION OF CARBON DIOXIDE TO METHANOL
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Page/Page column 14, (2019/10/29)
The present disclosure relates to a new catalytic process for the production of methanol from carbon dioxide, comprising: (1) the conversion of carbon dioxide and hydrogen to formic acid or formate salts; (2) converting the formic acid or formate salts to diformate esters of diols; (3) hydrogenating the diformate esters to methanol and diols. The diols produced from the hydrogenation reaction can be recovered and re-used to prepare the diformate esters.
Hydrogenation of amides catalyzed by a combined catalytic system of a Ru complex with a zinc salt
Kita, Yusuke,Higuchi, Takafumi,Mashima, Kazushi
supporting information, p. 11211 - 11213 (2014/09/30)
Addition of catalytic amounts of zinc salts facilitated the hydrogenation of amides catalyzed by a ruthenium complex bearing 2-(diphenylphosphino) ethanamine (L1). The combined catalytic system of the ruthenium complex [RuCl2(L1)2] with a zinc salt such as Zn(OCOCF 3)2 mediated hydrogenation of various amides under mild conditions to afford the corresponding primary alcohols.
