50289-57-1

Basic information

• Product Name: Phosphonic acid, [(4-bromophenyl)methyl]-, bis(1-methylethyl) ester
• CAS NO: 50289-57-1
• Molecular Formula: C13H20BrO3P
• Molecular Weight: 335.178
• Mol File: 50289-57-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [(4-bromophenyl)methyl]-, bis(1-methylethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [(4-bromophenyl)methyl]-, bis(1-methylethyl) ester(50289-57-1)
• EPA Substance Registry System: Phosphonic acid, [(4-bromophenyl)methyl]-, bis(1-methylethyl) ester(50289-57-1)

Safety Data

• Hazardous Substances Data: 50289-57-1(Hazardous Substances Data)

Upstream product

• 691-96-3 diisopropyl phosphite 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 116-17-6 triisopropyl phosphite 
• 1809-20-7 diisopropyl hydrogenphosphonate 

Downstream Products

• 430535-27-6 diisopropyl 4-aminobenzylphosphonate 
• 57082-98-1 (E)-1-bromo-4-(4-chlorostyryl)benzene 

Relevant articles and documents

Functionalised phosphonate ester supported lanthanide (Ln = La, Nd, Dy, Er) complexes

A series of phosphonate ester supported lanthanide complexes bearing functionalities for subsequent immobilisation on semiconductor surfaces are prepared. Six phosphonate ester ligands (L1-L6) with varying aromatic residues are synthesised. Subsequent com

Reactivity of the acids of trivalent phosphorus and their derivatives. Part VI. The reaction of the >P-O- anions with benzyl bromides para-substituted in the phenyl ring

The reaction of p-substituted benzyl bromides with the >P-O- ions in THF, alcohols and toluene as the solvents is described. According to the reduction potential of the p-substituted benzyl bromides and the solvent used the formation of the P-C bond, debromination and/or dimerization occur. The principal process is believed to be X-philic substitution, the dimers are formed through a secondary process via SET from the p-substituted benzyl anions into the p-substituted benzyl bromides.